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ASTM D 2425 : 2021

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Hydrocarbon Types in Middle Distillates by Mass Spectrometry
Available format(s)

Hardcopy , PDF

Superseded date

18-01-2024

Language(s)

English

Published date

17-06-2021

1.1This test method covers an analytical scheme using the mass spectrometer to determine the hydrocarbon types present in conventional and synthesized hydrocarbons that have a boiling range of 160 °C to 343 °C (320 °F to 650 °F), 5 % to 95 % by volume  as determined by Test Method D86. Samples with average carbon number value of paraffins between C12 and C16 and containing paraffins from C10 and C18 can be analyzed. Eleven hydrocarbon types are determined. These include: paraffins, noncondensed cycloparaffins, condensed dicycloparaffins, condensed tricycloparaffins, alkylbenzenes, indans or tetralins, or both, CnH 2n-10 (indenes, etc.), naphthalenes, CnH2n-14  (acenaphthenes, etc.), CnH 2n-16 (acenaphthylenes, etc.), and tricyclic aromatics.

Note 1:This test method was developed on Consolidated Electrodynamics Corporation Type 103 Mass Spectrometers. Operating parameters for users with a Quadrupole Mass Spectrometer are provided.

1.2This test method is intended for use with full boiling range products that contain no significant olefin content.

Biodiesel (FAME components) could interfere with the separation of the sample and the characteristic mass fragments of FAME compounds are not defined in the procedure.

Hydrocarbons containing tertiary carbon fragments, sometimes found in synthetic aviation fuels, will interfere with the characteristic mass fragments of paraffins and result in a false, elevated cycloparaffin content.

Note 2:“No significant olefin content” for this method means <2.0 % by volume by Test Method D1319.

1.3The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific warning statement, see 11.1.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 02
DocumentType
Test Method
Pages
15
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 5186 : 2020 Standard Test Method for Determination of the Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels By Supercritical Fluid Chromatography
ASTM D 8302 : 2020 Standard Test Method for Determination of Cycloparaffin Content in Saturated ATJ-SPK Jet Fuel Gas Chromatography
ASTM D 4054 : 2020 : REV C Standard Practice for Evaluation of New Aviation Turbine Fuels and Fuel Additives
ASTM D 7566 : 2020 : REV C Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons
ASTM F 715 : 2007 : R2018 Standard Test Methods for Coated Fabrics Used for Oil Spill Control and Storage
ASTM D 6618 : 2016 Standard Test Method for Evaluation of Engine Oils in Diesel Four-Stroke Cycle Supercharged 1M-PC Single Cylinder Oil Test Engine
ASTM D 8144 : 2018 : EDT 1 Standard Test Method for Separation and Determination of Aromatics, Nonaromatics, and FAME Fractions in Middle Distillates by Solid-Phase Extraction and Gas Chromatography
ASTM D 6750 : 2019 Standard Test Methods for Evaluation of Engine Oils in a High-Speed, Single-Cylinder Diesel Engine—1K Procedure (0.4 % Fuel Sulfur) and 1N Procedure (0.04 % Fuel Sulfur)
ASTM D 6681 : 2017 Standard Test Method for Evaluation of Engine Oils in a High Speed, Single-Cylinder Diesel Engine—Caterpillar 1P Test Procedure
ASTM D 6591 : 2019 Standard Test Method for Determination of Aromatic Hydrocarbon Types in Middle Distillates—High Performance Liquid Chromatography Method with Refractive Index Detection
ASTM D 2549 : 2002 : R2017 Standard Test Method for Separation of Representative Aromatics and Nonaromatics Fractions of High-Boiling Oils by Elution Chromatography
ASTM D 6618 : 2023 Standard Test Method for Evaluation of Engine Oils in Diesel Four-Stroke Cycle Supercharged 1M-PC Single Cylinder Oil Test Engine
ASTM D 7566 : 2023 : REV B Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons
ASTM F 715 : 2007 : R2023 Standard Test Methods for Coated Fabrics Used for Oil Spill Control and Storage
ASTM D 6681 : 2023 Standard Test Method for Evaluation of Engine Oils in a High Speed, Single-Cylinder Diesel Engine—Caterpillar 1P Test Procedure
ASTM D 6750 : 2023 Standard Test Methods for Evaluation of Engine Oils in a High-Speed, Single-Cylinder Diesel Engine—1K Procedure (0.4 % Fuel Sulfur) and 1N Procedure (0.04 % Fuel Sulfur)
ASTM D 5186 : 2022 Standard Test Method for Determination of the Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels By Supercritical Fluid Chromatography
ASTM D 4054 : 2023 Standard Practice for Evaluation of New Aviation Turbine Fuels and Fuel Additives
ASTM D 8144 : 2022 Standard Test Method for Separation and Determination of Aromatics, Nonaromatics, and FAME Fractions in Middle Distillates by Solid-Phase Extraction and Gas Chromatography

ASTM D 86 : 2023 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 1319 : 2018 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
ASTM D 2549 : 2023 Standard Test Method for Separation of Representative Aromatics and Nonaromatics Fractions of High-Boiling Oils by Elution Chromatography
ASTM D 86 : 2020 : REV A Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 86 : 2018 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 86 : 2019 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 6300 : 2021 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 86 : 2012 Standard Test Method for Distillation of Petroleum Products at Atmospheric Pressure
ASTM D 6300 : 2023 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 6300 : 2023 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 86 : 2020 : REV B Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 86 : 2016 : REV A Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 6379 : 2021 : EDT 1 Standard Test Method for Determination of Aromatic Hydrocarbon Types in Aviation Fuels and Petroleum Distillates—High Performance Liquid Chromatography Method with Refractive Index Detection
ASTM D 86 : 2020 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 6379 : 2021 Standard Test Method for Determination of Aromatic Hydrocarbon Types in Aviation Fuels and Petroleum Distillates—High Performance Liquid Chromatography Method with Refractive Index Detection
ASTM D 86 : 2015 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 86 : 2017 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
ASTM D 1319 : 2019 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
ASTM D 6379 : 2011 : R2019 Standard Test Method for Determination of Aromatic Hydrocarbon Types in Aviation Fuels and Petroleum Distillates—High Performance Liquid Chromatography Method with Refractive Index Detection

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