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ASTM D 4519 : 2016

Current
Current

The latest, up-to-date edition.

Standard Test Method for On-Line Determination of Anions and Carbon Dioxide in High Purity Water by Cation Exchange and Degassed Cation Conductivity
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

01-06-2016

This on-line test method includes hydrogen exchange and degassing by heating or gas stripping and provides means for determining anions (such as Cl−, SO4—, NO3−, and F−) at levels as low as 2 μg/L (2 ppb) and carbon dioxide at the level of 0.01 to 10 mg/L (ppm) at 25°C in high purity water and in steam and water samples in power plants by measuring electrical conductivity.

1.1This on-line test method includes hydrogen exchange and degassing by heating or gas stripping and provides means for determining anions (such as Cl, SO4, NO3, and F) at levels as low as 2 μg/L (2 ppb) and carbon dioxide at the level of 0.01 to 10 mg/L (ppm) at 25°C in high purity water and in steam and water samples in power plants by measuring electrical conductivity.

1.2The conductivity of all anions (except OH) is determined and not the conductivity of an individual anion if more than one is present. If only one anion is present (such as Cl or SO4—−), reference to Section 4, Table 1 and Table 2 or Figs. 1-3 provides the chloride or sulfate and CO2 concentration.

1.3This test method has been improved in accuracy by using a modern microprocessor instrument for conductivity and temperature measurement and appropriate temperature compensation algorithms for compensation, by using final sample cooling to 25°C, or both.

1.4The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.

1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Committee
D 19
DocumentType
Test Method
Pages
7
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

ASTM D 5391 : 2014 Standard Test Method for Electrical Conductivity and Resistivity of a Flowing High Purity Water Sample (Withdrawn 2023)
ASTM D 6504 : 2011 : R2016 : EDT 1 Standard Practice for On-Line Determination of Cation Conductivity in High Purity Water
ASTM D 5997 : 2015 Standard Test Method for On-Line Monitoring of Total Carbon, Inorganic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
ASTM D 6317 : 2015 Standard Test Method for Low Level Determination of Total Carbon, Inorganic Carbon and Organic Carbon in Water by Ultraviolet, Persulfate Oxidation, and Membrane Conductivity Detection
ASTM D 1125 : 2014 Standard Test Methods for Electrical Conductivity and Resistivity of Water (Withdrawn 2023)

ASTM D 3370 : 1995 : REV A : R2003 : EDT 1 Standard Practices for Sampling Water from Closed Conduits
ASTM D 1129 : 2003 Standard Terminology Relating to Water
ASTM D 1129 : 2013 Standard Terminology Relating to Water
ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1129 : 2013 : R2020 : EDT 2 Standard Terminology Relating to Water
ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
ASTM D 1125 : 2014 Standard Test Methods for Electrical Conductivity and Resistivity of Water (Withdrawn 2023)
ASTM D 1129 : 2006 Standard Terminology Relating to Water
ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 2777 : 2021 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1066 : 2018 Standard Practice for Sampling Steam
ASTM D 3370 : 2010 Standard Practices for Sampling Water from Closed Conduits
ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1066 : 2006 Standard Practice for Sampling Steam
ASTM D 1066 : 2018 : EDT 1 Standard Practice for Sampling Steam
ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 1129 : 2013 : R2020 : EDT 1 Standard Terminology Relating to Water
ASTM D 3370 : 2008 Standard Practices for Sampling Water from Closed Conduits
ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2006 : REV A Standard Terminology Relating to Water
ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
ASTM D 1129 : 2003 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2002 Standard Terminology Relating to Water
ASTM D 1066 : 1997 : R2001 Standard Practice for Sampling Steam
ASTM D 1125 : 1995 : R1999 Standard Test Methods for Electrical Conductivity and Resistivity of Water
ASTM D 1193 : 1991 Standard Specification for Reagent Water
ASTM D 1066 : 2011 Standard Practice for Sampling Steam
ASTM D 1129 : 2004 Standard Terminology Relating to Water
ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 3370 : 2018 Standard Practices for Sampling Water from Flowing Process Streams
ASTM D 1129 : 2002 : REV A Standard Terminology Relating to Water
ASTM D 3370 : 1976 Standard Practices for Sampling Water
ASTM D 1125 : 1995 : R2005 Standard Test Methods for Electrical Conductivity and Resistivity of Water
ASTM D 1125 : 2023 Standard Test Methods for Electrical Conductivity and Resistivity of Water
ASTM D 1193 : 1970 Standard Specification For Reagent Water
ASTM D 1193 : 2006 Standard Specification for Reagent Water
ASTM D 3370 : 1995 : REV A : R1999 : EDT 1 Standard Practices for Sampling Water from Closed Conduits
ASTM D 1193 : 1999 Standard Specification for Reagent Water
ASTM D 1129 : 2010 Standard Terminology Relating to Water
ASTM D 3370 : 2007 Standard Practices for Sampling Water from Closed Conduits
ASTM D 1129 : 2006 : REV A : EDT 1 Standard Terminology Relating to Water
ASTM D 1129 : 2001 Standard Terminology Relating to Water
ASTM D 1129 : 2004 : EDT 1 Standard Terminology Relating to Water
ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 1125 : 1995 : R2009 Standard Test Methods for Electrical Conductivity and Resistivity of Water

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