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ASTM D 5769 : 2015

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
Available format(s)

Hardcopy , PDF

Superseded date

10-05-2023

Language(s)

English

Published date

22-12-2015

This test method covers the determination of benzene, toluene, other specified individual aromatic compounds, and total aromatics in finished motor gasoline, including gasolines containing oxygenated blending components, by gas chromatography/mass spectrometry (GC/MS).

1.1This test method covers the determination of benzene, toluene, other specified individual aromatic compounds, and total aromatics in finished motor gasoline, including gasolines containing oxygenated blending components, by gas chromatography/mass spectrometry (GC/MS).

1.2This test method has been tested for the following concentration ranges, in liquid volume percent, for the following aromatics: benzene, 0.1 % to 4 %; toluene, 1 % to 13 %; and total (C6 to C12) aromatics, 10 % to 42 %. The round-robin study did not test the method for individual hydrocarbon process streams in a refinery, such as reformates, fluid catalytic cracked naphthas, and so forth, used in the blending of gasolines.

1.3Results are reported to the nearest 0.01 % for benzene and 0.1 % for the other aromatics by liquid volume.

1.4This test method includes a relative bias section for EPA spark-ignition engine fuel benzene regulations reporting based on Practice D6708 accuracy assessment between Test Method D5769 and Test Method D3606 as a possible Test Method D5769 alternative to Test Method D3606. The Practice D6708 derived correlation equation is only applicable for blended fuels in the benzene concentration range from 0.0 % to 2.50 % by volume as measured by Test Method D5769. The applicable Test Method D3606 range for benzene is from 0.0 % to 2.47 % by volume as reported by Test Method D3606.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to its use.

Committee
D 02
DocumentType
Test Method
Pages
13
ProductNote
Technical commitiee,ICS Code,Supersition and pages has been updated.
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 6122 : 2022 Standard Practice for Validation of the Performance of Multivariate Online, At-Line, Field and Laboratory Infrared Spectrophotometer, and Raman Spectrometer Based Analyzer Systems
ASTM D 8321 : 2022 Standard Practice for Development and Validation of Multivariate Analyses for Use in Predicting Properties of Petroleum Products, Liquid Fuels, and Lubricants based on Spectroscopic Measurements
ASTM D 6708 : 2021 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6593 : 2018 : EDT 1 Standard Test Method for Evaluation of Automotive Engine Oils for Inhibition of Deposit Formation in a Spark-Ignition Internal Combustion Engine Fueled with Gasoline and Operated Under Low-Temperature, Light-Duty Conditions
ASTM D 8275 : 2022 Standard Specification for Gasoline-like Test Fuel for Compression-Ignition Engines
ASTM D 3606 : 2022 Standard Test Method for Determination of Benzene and Toluene in Spark Ignition Fuels by Gas Chromatography
ASTM D 8071 : 2021 Standard Test Method for Determination of Hydrocarbon Group Types and Select Hydrocarbon and Oxygenate Compounds in Automotive Spark-Ignition Engine Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
ASTM D 6839 : 2021 : REV A Standard Test Method for Hydrocarbon Types, Oxygenated Compounds, Benzene, and Toluene in Spark Ignition Engine Fuels by Multidimensional Gas Chromatography
ASTM D 1319 : 2020 : REV A Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
ASTM D 5580 : 2021 Standard Test Method for Determination of Benzene, Toluene, Ethylbenzene, <emph type="ital"> p/m</emph>-Xylene, <emph type="ital">o</emph>-Xylene, C<inf>9</inf> and Heavier Aromatics, and Total Aromatics in Finished Gasoline by Gas Chromatography
ASTM D 6277 : 2007 : R2022 Standard Test Method for Determination of Benzene in Spark-Ignition Engine Fuels Using Mid Infrared Spectroscopy
ASTM D 8071 : 2019 Standard Test Method for Determination of Hydrocarbon Group Types and Select Hydrocarbon and Oxygenate Compounds in Automotive Spark-Ignition Engine Fuel Using Gas Chromatography with Vacuum Ultraviolet Absorption Spectroscopy Detection (GC-VUV)
ASTM D 1319 : 2019 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
ASTM D 6708 : 2019 : REV A Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 5580 : 2015 Standard Test Method for Determination of Benzene, Toluene, Ethylbenzene, <emph type="ital"> p/m</emph>-Xylene, <emph type="ital">o</emph>-Xylene, C<inf>9</inf> and Heavier Aromatics, and Total Aromatics in Finished Gasoline by Gas Chromatography
ASTM D 6708 : 2019 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1319 : 2018 Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption

ASTM D 4057 : 2019 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4057 : 1995 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 3606 : 2007 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 1298 : 2012 : REV A Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 6708 : 2018 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 3606 : 2010 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 6708 : 2015 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2013 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 4052 : 1996 : R2002 : EDT 1 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
ASTM D 3606 : 2004 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 1298 : 2012 : REV B Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 6708 : 2007 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 4057 : 2012 : R2018 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4052 : 2018 : REV A Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 6708 : 2016 : REV B Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2006 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 3606 : 2006 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 1298 : 1999 : R2005 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 4052 : 2009 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 4057 : 1981 : EDT 2 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 1298 : 2012 : REV B : R2017 Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 1298 : 2012 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 1298 : 1999 : EDT 2 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 6708 : 2004 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 4307 : 1999 : R2004 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D 6708 : 2019 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2016 : REV A Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2008 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1298 : 1999 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 4057 : 2006 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4052 : 2011 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 4052 : 2016 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 3606 : 2017 Standard Test Method for Determination of Benzene and Toluene in Spark Ignition Fuels by Gas Chromatography
ASTM D 3606 : 2006 : EDT 1 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 4057 : 2012 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4307 : 1999 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D 6708 : 2001 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1298 : 1999 : EDT 1 Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 4307 : 2017 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D 6708 : 2001 : EDT 1 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2005 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2013 : EDT 1 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 3606 : 2004 : REV A Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 3606 : 2010 : EDT 1 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 6708 : 2016 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 4052 : 1996 Standard Test Method for Density and Relative Density of Liquids by Digital Density Meter
ASTM D 4307 : 1999 : R2010 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D 6708 : 2019 : REV A Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 3606 : 1999 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 1298 : 1985 : R1990 : EDT 1 Standard Practice for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
ASTM D 4052 : 2015 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 4057 : 1995 : R2000 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4307 : 1999 : R2015 Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards
ASTM D 3606 : 1992 Standard Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
ASTM D 4057 : 2006 : R2011 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4052 : 2018 Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

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