ASTM D 7423 : 2017
Superseded
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
View Superseded by
superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
Standard Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography and Flame Ionization Detection
Available format(s)
Hardcopy , PDF
Superseded date
20-03-2023
Language(s)
English
Published date
10-07-2017
This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection.
1.1This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection. This test method is applicable when the hydrocarbon matrices have a final boiling point not greater than 200 °C. Oxygenate compounds include, but are not limited to, those listed in Table 1. The linear working range for oxygenates is 0.50 mg/kg to 100 mg/kg.
TABLE 1 Oxygenates and Typical Retention Times
| Components | Retention Time (min) |
| Dimethyl ether | 6.18 |
| Diethyl ether | 8.44 |
| Acetaldehyde | 8.89 |
| Ethyl tert-butyl ether | 10.66 |
| Methyl tert-butyl ether (MTBE) | 10.92 |
| Diisopropyl ether | 11.22 |
| Propionaldehyde (Propanal) | 12.00 |
| Tertiary amyl methyl ether (TAME) | 13.19 |
| Propyl ether | 14.00 |
| Isobutylaldehyde | 14.10 |
| Butylaldehyde | 14.50 |
| Methanol | 14.91 |
| Acetone | 15.39 |
| Isovaleraldehyde | 16.00 |
| Valeraldehyde | 16.10 |
| 2-Butanone (MEK) | 17.14 |
| Ethanol | 17.51 |
| N-propyl alcohol and isopropanol | 19.20 (co-elution) |
| Allyl Alcohol | 20.00 |
| Isobutanol, Tert-butyl alcohol, Sec-Butanol | 20.24 (co-elution) |
| N-butanol | 20.84 |
1.2This test method is intended to determine the mass concentration of each oxygenate in the hydrocarbon matrix. Oxygenate compound identification is determined by reference standards and column elution retention order.
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
| Committee |
D 02
|
| DocumentType |
Test Method
|
| Pages |
9
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Superseded
|
| SupersededBy | |
| Supersedes |
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| ASTM D 4175 : 2014 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2009 : REV A : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6300 : 2020 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 4175 : 2008 : REV B : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6849 : 2022 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 6300 : 2013 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2005 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2010 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6300 : 2014 : REV A : EDT 1 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 1265 : 1997 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
| ASTM D 4175 : 2005 : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2013 : EDT 1 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM E 177 : 1990 : REV A : R1996 | Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods |
| ASTM D 4175 : 2015 : REV C | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2017 : REV A | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2020 : REV B | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 4175 : 2017 : REV A : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2017 : REV B | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6300 : 2017 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 6299 : 2009 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 1835 : 1997 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 6849 : 2002 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 6300 : 2017 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2008 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2020 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2013 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2017 : REV B | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2021 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2009 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6849 : 2002 : R2012 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 6299 : 2010 : EDT 1 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2022 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2022 : EDT 1 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6300 : 2016 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2009 : REV A : EDT 4 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2009 : REV A : EDT 3 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6849 : 2002 : R2007 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 6300 : 2004 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2018 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1835 : 2018 : REV A | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 1835 : 2012 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 6300 : 2019 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2001 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2020 : REV B : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 4175 : 2001 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2005 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2022 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6300 : 2021 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6300 : 2019 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2002 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6849 : 2013 : R2021 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 6300 : 2020 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2000 | Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6299 : 2010 : EDT 2 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6299 : 2016 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2015 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2002 : REV A : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2019 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 1835 : 2003 : REV A | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 6300 : 2020 : REV B | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2000 : REV A | Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6300 : 2006 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2009 : REV A : EDT 5 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2016 : REV C | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 4175 : 2015 : REV B | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6300 : 2014 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM E 355 : 1996 : R2021 : EDT 1 | Standard Practice for Gas Chromatography Terms and Relationships |
| ASTM D 1835 : 2003 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 6300 : 2015 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2015 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6300 : 1999 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 1835 : 2013 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 4175 : 2009 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 1835 : 2020 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 4175 : 2016 : REV B | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6299 : 2020 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2002 : REV A : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2008 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2008 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 1835 : 2018 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 4175 : 2002 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6849 : 2013 | Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods |
| ASTM D 4175 : 2000 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 4175 : 2016 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1265 : 2004 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
| ASTM D 6300 : 2013 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 6299 : 2002 : EDT 1 | Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2019 : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1835 : 2022 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 4175 : 2022 : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1835 : 2016 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 6300 : 2008 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 6300 : 2003 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 1265 : 2011 : R2017 : EDT 1 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
| ASTM D 6300 : 2007 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 6299 : 2022 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2017 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1835 : 2011 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 1265 : 2005 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
| ASTM D 6300 : 2002 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2009 : REV A : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 1265 : 2004 : REV A | Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method) |
| ASTM D 1265 : 2011 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
| ASTM D 4175 : 2018 : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 4175 : 2016 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6300 : 2016 : REV A | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM E 355 : 1996 : R2014 | Standard Practice for Gas Chromatography Terms and Relationships |
| ASTM D 6299 : 2007 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6299 : 2007 : EDT 1 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 6299 : 2020 : REV A | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2017 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 1265 : 2022 | Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method |
| ASTM D 6299 : 2017 | Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance |
| ASTM D 4175 : 2019 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
| ASTM D 6300 : 2014 | Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants |
| ASTM D 4175 : 2015 : REV B : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 1835 : 2005 | Standard Specification for Liquefied Petroleum (LP) Gases |
| ASTM D 4175 : 2008 : REV B | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
| ASTM D 6299 : 2002 | Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance |
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