ASTM D 859 : 2016

1.1This test method covers the determination of silica in water and waste water; however, the analyst should recognize that the precision and accuracy statements for reagent water solutions may not apply to waters of different matrices.

1.2This test method is a colorimetric method that determines molybdate-reactive silica. It is applicable to most waters, but some waters may require filtration and dilution to remove interferences from color and turbidity. This test method is useful for concentrations as low as 20 μg/L.

1.3This test method covers the photometric determination of molybdate-reactive silica in water. Due to the complexity of silica chemistry, the form of silica measured is defined by the analytical method as molybdate-reactive silica. Those forms of silica that are molybdate-reactive include dissolved simple silicates, monomeric silica and silicic acid, and an undetermined fraction of polymeric silica.

1.4The useful range of this test method is from 20 to 1000 μg/L at the higher wavelength (815 nm) and 0.1 to 5 mg/L at the lower wavelength (640 nm). It is particularly applicable to treated industrial waters. It may be applied to natural waters and wastewaters following filtration or dilution, or both. For seawater or brines, this test method is applicable only if matched matrix standards or standard addition techniques are employed.

1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

1.7Former Test Method A (Gravimetric—Total Silica) was discontinued. Refer to Appendix X1 for historical information.