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EN 16693:2015

Current
Current

The latest, up-to-date edition.

Water quality - Determination of organochlorine pesticides (OCP) in whole water samples - Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS)
Published date

23-09-2015

European foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interferences
5 Reagents
6 Apparatus
7 Sampling
8 Procedure
9 Calibration
10 Calculation of the results
11 Expression of results
12 Test report
Annex A (informative) - Suitable gas chromatographic
        conditions and example chromatograms -
        GC-conditions of example chromatograms in
        Figure A.1
Annex B (informative) - Repeatability and reproducibility data
Annex C (informative) - Examples of suitable SPE-disks
Annex D (informative) - Examples of internal standards
Bibliography

This European Standard specifies a method for the determination of selected organochlorine pesticides (OCP, see Table 1), in water samples. The method uses solid-phase extraction with SPE-disks followed by gas chromatography-mass spectrometry (GC-MS). It is applicable to the analysis of OCPs in surface water containing suspended particulate matter (SPM) up to 500 mg/l (whole water samples), drinking water and groundwater. The lower limit of the working range depends on the matrix, on the specific compound to be analyzed and on the sensitivity of the mass spectrometric detection unit. For compounds listed in Table 1 the limit of determination (LOQ) it is at least 30 % of the corresponding AA-EQS value (0,000 15 µg/l to 0,1 µg/l) according to the requirements of the European EQS Directive 2008/105/EC for both inland surface waters and other surface waters.This method may be used for the analysis of other OCPs not listed in Table 1 or other types of water. However, it is necessary to verify its applicability before use.(...)

Committee
CEN/TC 230
DevelopmentNote
Supersedes PREN 16693. (09/2015)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current

Standards Relationship
SN EN 16693 : 2015 Identical
BS EN 16693:2015 Identical
NEN EN 16693 : 2015 Identical
I.S. EN 16693:2015 Identical
NF EN 16693 : 2015 Identical
NBN EN 16693 : 2015 Identical
DIN EN 16693:2015-12 Identical
NS EN 16693 : 2015 Identical
UNI EN 16693 : 2015 Identical
UNE-EN 16693:2016 Identical
DIN EN 16693 E : 2015 Identical
PN EN 16693 : 2015 Identical

ISO 22892:2006 Soil quality Guidelines for the identification of target compounds by gas chromatography and mass spectrometry
ISO 5667-3:2012 Water quality Sampling Part 3: Preservation and handling of water samples
ISO 5667-1:2006 Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
EN ISO 5667-3:2012 Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012)
ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
ISO 8466-1:1990 Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
EN ISO 22892:2011 Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006)
ISO/TS 28581:2012 Water quality — Determination of selected non-polar substances — Method using gas chromatography with mass spectrometric detection (GC-MS)
EN ISO 5667-1 : 2006 COR 2007 WATER QUALITY - SAMPLING - PART 1: GUIDANCE ON THE DESIGN OF SAMPLING PROGRAMMES AND SAMPLING TECHNIQUES

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