ASTM C 697 : 2016
Current
Current
The latest, up-to-date edition.
Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Plutonium Dioxide Powders and Pellets
Available format(s)
Hardcopy , PDF
Language(s)
English
Published date
01-06-2016
1.1These test methods cover procedures for the chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets to determine compliance with specifications.
1.2The analytical procedures appear in the following order:
| Sections | |
| Plutonium Sample Handling | 8 to 10 |
| Plutonium by Controlled-Potential Coulometry | 2 |
| Plutonium by Ceric Sulfate Titration | 3 |
| Plutonium by Amperometric Titration with Iron(II) | 2 |
| Plutonium by Diode Array Spectrophotometry | 3 |
| Nitrogen by Distillation Spectrophotometry Using Nessler | 11 to 18 |
| Carbon (Total) by Direct Combustion–Thermal Conductivity | 19 to 29 |
| Total Chlorine and Fluorine by Pyrohydrolysis | 30 to 37 |
| Sulfur by Distillation Spectrophotometry | 38 to 46 |
| Plutonium Isotopic Analysis by Mass Spectrometry | 4 |
| Rare Earth Elements by Spectroscopy | 47 to 54 |
| Trace Elements by Carrier–Distillation Spectroscopy | 55 to 62 |
| (Alternative: Impurities by ICP-AES or ICP-MS) | |
| Impurity Elements by Spark-Source Mass Spectrography | 63 to 69 |
| Moisture by the Coulometric Electrolytic Moisture Analyzer | 70 to 77 |
| Total Gas in Reactor-Grade Plutonium Dioxide Pellets | 5 |
| Plutonium-238 Isotopic Abundance by Alpha Spectrometry | 3 |
| Americium-241 in Plutonium by Gamma-Ray Spectrometry | 2 |
| Rare Earths By Copper Spark-Spectroscopy | 78 to 87 |
| Plutonium Isotopic Analysis by Mass Spectrometry | 88 to 96 |
| Oxygen-To-Metal Atom Ratio by Gravimetry | 97 to 104 |
1.3The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Sections 6, 16.2.5, 44.7, 51.9 and 92.5.1.
| Committee |
C 26
|
| DocumentType |
Test Method
|
| Pages |
25
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
| Supersedes |
| ASTM C 1206 : 2002 : R2010 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration (Withdrawn 2015) |
| ASTM C 1168 : 2023 | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
| ASTM C 1165 : 2023 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1307 : 2015 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1415 : 2001 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 1108 : 2023 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 859 : 2023 | Standard Terminology Relating to Nuclear Materials |
| ASTM C 1415 : 1999 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 859 : 2014 : REV B | Standard Terminology Relating to Nuclear Materials |
| ASTM C 757 : 1990 : R1996 : EDT 1 | Standard Specification for Nuclear-Grade Plutonium Dioxide Powder, Sinterable |
| ASTM C 859 : 2024 | Standard Terminology Relating to Nuclear Materials |
| ASTM D 1193 : 1977 : R1983 : EDT 1 | Standard Specification for Reagent Water |
| ASTM C 1206 : 1991 : R1996 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration |
| ASTM C 1268 : 1994 : R2008 | Standard Test Method for Quantitative Determination of Americium 241 in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 1637 : 2013 | Standard Test Method for the Determination of Impurities in Plutonium Metal: Acid Digestion and Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) Analysis |
| ASTM C 1268 : 2015 | Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 1672 : 2017 | Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer |
| ASTM C 1235 : 1999 | Standard Test Method for Plutonium by Titanium(III)/Cerium(IV) Titration (Withdrawn 2005) |
| ASTM C 1233 : 2003 | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 1233 : 1998 | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 757 : 2016 : EDT 1 | Standard Specification for Nuclear-Grade Plutonium Dioxide Powder for Light Water Reactors |
| ASTM C 1165 : 1990 : R2005 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<sub>2</sub>SO<sub>4</sub> at a Platinum Working Electrode |
| ASTM C 1068 : 1996 : EDT 1 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1165 : 2022 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1108 : 2017 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1307 : 2002 : R2008 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM D 4327 : 2011 | Standard Test Method for Anions in Water by Suppressed Ion Chromatography |
| ASTM C 1672 : 2023 | Standard Test Method for Determination of the Uranium, Plutonium or Americium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer |
| ASTM C 1168 : 2015 | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
| ASTM C 1432 : 2023 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1206 : 2002 | Standard Test Method for Plutonium by Iron (II)/Chromium (VI) Amperometric Titration |
| ASTM C 1165 : 1990 : R2000 : EDT 1 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<sub>2</sub>SO<sub>4</sub> at a Platinum Working Electrode |
| ASTM C 1068 : 2003 : R2011 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM E 60 : 2011 : R2016 | Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry |
| ASTM C 1432 : 2003 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1637 : 2006 | Standard Test Method for the Determination of Impurities in Plutonium Metal: Acid Digestion and Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) Analysis |
| ASTM D 1193 : 2006 : R2011 | Standard Specification for Reagent Water |
| ASTM C 1108 : 1999 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1415 : 2014 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance By Alpha Spectrometry |
| ASTM C 1432 : 2003 : R2008 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1625 : 2019 | Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances by Thermal Ionization Mass Spectrometry |
| ASTM C 1068 : 2015 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1415 : 2001 : REV A : R2007 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance by Alpha Spectrometry |
| ASTM C 1307 : 1995 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 757 : 2016 : R2021 | Standard Specification for Nuclear-Grade Plutonium Dioxide Powder for Light Water Reactors |
| ASTM C 1068 : 2021 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1165 : 2012 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM D 4327 : 2003 | Standard Test Method for Anions in Water by Chemically Suppressed Ion Chromatography |
| ASTM C 1432 : 2015 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1672 : 2007 : R2014 | Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer |
| ASTM C 1233 : 2015 : R2021 | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 1268 : 1994 : R2000 | Standard Test Method for Quantitative Determination of Americium 241 in Plutonium by Gamma-Ray Spectrometry |
| ASTM C 859 : 2022 | Standard Terminology Relating to Nuclear Materials |
| ASTM C 859 : 2022 : REV A | Standard Terminology Relating to Nuclear Materials |
| ASTM C 1625 : 2005 | Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances by Thermal Ionization Mass Spectrometry |
| ASTM D 1193 : 1991 | Standard Specification for Reagent Water |
| ASTM C 1233 : 2015 | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 1068 : 2003 | Standard Guide for Qualification of Measurement Methods by a Laboratory Within the Nuclear Industry |
| ASTM C 1672 : 2007 | Standard Test Method for Determination of Uranium or Plutonium Isotopic Composition or Concentration by the Total Evaporation Method Using a Thermal Ionization Mass Spectrometer |
| ASTM D 4327 : 2017 | Standard Test Method for Anions in Water by Suppressed Ion Chromatography |
| ASTM C 1307 : 2014 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1268 : 2023 | Standard Test Method for Quantitative Determination of <sup>241</sup>Am in Plutonium by Gamma-Ray Spectrometry |
| ASTM D 4327 : 1997 | Standard Test Method for Anions in Water by Chemically Suppressed Ion Chromatography |
| ASTM C 1637 : 2021 | Standard Test Method for Determination of Impurities in Plutonium Materials—Acid Digestion and Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) Analysis |
| ASTM C 1307 : 2021 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM C 1108 : 2022 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1108 : 2012 | Standard Test Method for Plutonium by Controlled-Potential Coulometry |
| ASTM C 1168 : 2001 | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
| ASTM C 1165 : 2017 | Standard Test Method for Determining Plutonium by Controlled-Potential Coulometry in H<inf>2</inf>SO<inf>4</inf> at a Platinum Working Electrode |
| ASTM C 1168 : 1990 : R1995 : EDT 1 | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
| ASTM E 60 : 2011 : R2022 : EDT 1 | Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry |
| ASTM D 1193 : 1970 | Standard Specification For Reagent Water |
| ASTM E 115 : 1997 | Standard Practice for Photographic Processing in Optical Emission Spectrographic Analysis (Withdrawn 2002) |
| ASTM D 1193 : 2006 | Standard Specification for Reagent Water |
| ASTM C 1307 : 2002 | Standard Test Method for Plutonium Assay by Plutonium (III) Diode Array Spectrophotometry |
| ASTM D 1193 : 1999 | Standard Specification for Reagent Water |
| ASTM C 1432 : 1999 | Standard Test Method for Determination of Impurities in Plutonium: Acid Dissolution, Ion Exchange Matrix Separation, and Inductively Coupled Plasma-Atomic Emission Spectroscopic (ICP/AES) Analysis |
| ASTM C 1233 : 2009 | Standard Practice for Determining Equivalent Boron Contents of Nuclear Materials |
| ASTM C 1415 : 2018 | Standard Test Method for <sup>238</sup>Pu Isotopic Abundance By Alpha Spectrometry |
| ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
| ASTM C 1625 : 2012 | Standard Test Method for Uranium and Plutonium Concentrations and Isotopic Abundances by Thermal Ionization Mass Spectrometry |
| ASTM C 1168 : 2008 | Standard Practice for Preparation and Dissolution of Plutonium Materials for Analysis |
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