1.1This test method describes a procedure for sampling and analysis of selected volatile organic compounds (VOCs) in ambient, indoor, and workplace atmospheres. The test method is based on the collection of whole air samples in stainless steel canisters with specially treated (passivated) interior surfaces.

1.2For sample analysis, a portion of the sample is subsequently removed from the canister and the collected VOCs are selectively concentrated by adsorption or condensation onto a trap, subsequently released by thermal desorption, separated by gas chromatography, and measured by a low resolution mass spectrometric detector. This test method describes procedures for sampling into canisters to final pressures both above and below atmospheric pressure (respectively referred to as pressurized and subatmospheric pressure sampling).2

1.3This test method is applicable to specific VOCs that have been determined to be stable when stored in canisters (see Table 1). Numerous compounds, many of which are chlorinated VOCs, have been successfully tested for storage stability in pressurized canisters (1-4).3 Information on storage stability is also available for polar compounds (5-7). This test method has been documented for the compounds listed in Table 1 and performance results apply only to those compounds. A laboratory may determine other VOCs by this test method after completion of verification studies that include measurement of recovery as specified in 5.7 and that are as extensive as required to meet the performance needs of the customer and the given application.

1.4The procedure for collecting the sample involves the use of inlet lines, air filters, flow rate regulators for obtaining time-integrated samples, and in the case of pressurized samples, an air pump. Typical long-term fixed location canister samplers have been designed to automatically start and stop the sample collection process using electronically actuated valves and timers (8-10). Temporary or short-term canister samplers may require the user to manually start and stop sample collection. A weatherproof shelter may be required if the sampler is used outdoors. For the purposes of this test method, refer to Practice D1357 for practices and planning ambient sampling events.

1.5The organic compounds that have been successfully measured single-digit micrograms per cubic metre (µg/m³ (or single digit parts-per-billion by volume (ppbv)) concentration with this test method are listed in order of approximate retention time in Table 1. The test method is applicable to VOC concentrations ranging from the detection limit to approximately 1000 µg/m³ (300 ppbv). Above this concentration, smaller sample aliquots of sample gas may be analyzed or samples can be diluted with dry ultra-high-purity nitrogen or air or equivalent.

1.6The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.7This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Safety practices should be part of the user’s SOP manual.

1.8This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.