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ASTM D 974 : 2022

Current
Current

The latest, up-to-date edition.

Standard Test Method for Acid and Base Number by Color-Indicator Titration
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

20-01-2023

1.1This test method covers the determination of acidic or basic constituents (Note 1) in petroleum products3 and lubricants soluble or nearly soluble in mixtures of toluene and isopropyl alcohol. It is applicable for the determination of acids or bases whose dissociation constants in water are larger than 10−9; extremely weak acids or bases whose dissociation constants are smaller than 10−9 do not interfere. Salts react if their hydrolysis constants are larger than 10−9.

Note 1:In new and used oils, the constituents considered to have acidic characteristics include organic and inorganic acids, esters, phenolic compounds, lactones, resins, salts of heavy metals, and addition agents such as inhibitors and detergents. Similarly, constituents considered to have basic properties include organic and inorganic bases, amino compounds, salts of weak acids (soaps), basic salts of polyacidic bases, salts of heavy metals, and addition agents such as inhibitors and detergents.

Note 2:This test method is not suitable for measuring the basic constituents of many basic additive-type lubricating oils. Test Method D4739 can be used for this purpose.

1.2This test method can be used to indicate relative changes that occur in an oil during use under oxidizing conditions. Although the titration is made under definite equilibrium conditions, the method does not measure an absolute acidic or basic property that can be used to predict performance of an oil under service conditions. No general relationship between bearing corrosion and acid or base numbers is known.

Note 3:Oils, such as many cutting oils, rustproofing oils, and similar compounded oils, or excessively dark-colored oils, that cannot be analyzed for acid number by this test method due to obscurity of the color-indicator end point, can be analyzed by Test Method D664. The acid numbers obtained by this color-indicator test method need not be numerically the same as those obtained by Test Method D664, the base numbers obtained by this color indicator test method need not be numerically the same as those obtained by Test Method D4739, but they are generally of the same order of magnitude.

1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 02
DocumentType
Test Method
Pages
7
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

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ASTM D 3455 : 2011 : R2019 Standard Test Methods for Compatibility of Construction Material with Electrical Insulating Oil of Petroleum Origin
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ASTM D 1534 : 1995 : R2017 Standard Test Method for Approximate Acidity in Electrical Insulating Liquids by Color-Indicator Titration
ASTM D 7155 : 2020 Standard Practice for Evaluating Compatibility of Mixtures of Turbine Lubricating Oils
ASTM D 8045 : 2017 : EDT 1 Standard Test Method for Acid Number of Crude Oils and Petroleum Products by Catalytic Thermometric Titration
ASTM D 6439 : 2023 Standard Guide for Cleaning, Flushing, and Purification of Steam, Gas, and Hydroelectric Turbine Lubrication Systems
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ASTM D 6158 : 2023 Standard Specification for Mineral Hydraulic Oils
ASTM D 5222 : 2023 Standard Specification for Less Flammable High Molecular Weight Hydrocarbon Mineral Electrical Insulating Liquids
ASTM D 4174 : 2023 Standard Practice for Cleaning, Flushing, and Purification of Petroleum Fluid Hydraulic Systems
ASTM D 6751 : 2023 : REV A Standard Specification for Biodiesel Fuel Blendstock (B100) for Middle Distillate Fuels
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ASTM D 6224 : 2023 Standard Practice for In-Service Monitoring of Lubricating Oil for Auxiliary Power Plant Equipment
ASTM D 8045 : 2017 : R2023 Standard Test Method for Acid Number of Crude Oils and Petroleum Products by Catalytic Thermometric Titration

ASTM D 4057 : 2019 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 664 : 2017 : REV A Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration
ASTM D 4175 : 2022 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2023 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2022 : REV A : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4177 : 2022 Standard Practice for Automatic Sampling of Petroleum and Petroleum Products
ASTM D 4175 : 2023 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 4175 : 2023 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
ASTM D 664 : 2011 : REV A Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration
ASTM D 4739 : 2023 Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration
ASTM D 4177 : 2022 : EDT 1 Standard Practice for Automatic Sampling of Petroleum and Petroleum Products

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