1.1This guide covers an overview of the work of ASTM Committee G04 on Compatibility and Sensitivity of Materials in Oxygen-Enriched Atmospheres. It is a starting point for those asking the question: “What are the risks associated with my use of oxygen?” This guide is an introduction to the unique concerns that must be addressed in the handling of oxygen. The principal hazard is the prospect of ignition with resultant fire, explosion, or both. All fluid systems require design considerations, such as adequate strength, corrosion resistance, fatigue resistance, and pressure safety relief. In addition to these design considerations, one must also consider the ignition mechanisms that are specific to an oxygen-enriched system. This guide outlines these ignition mechanisms and the approach to reducing the risks.

1.2This guide also lists several of the recognized causes of oxygen system fires and describes the methods available to prevent them. Sources of information about the oxygen hazard and its control are listed and summarized. The principal focus is on Guides G63, G88, Practice G93, and Guide G94. Useful documentation from other resources and literature is also cited.

1.3The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in non-conformance with the standard.

1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements see Sections 8 and 11.