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BS 1427:2009

Current
Current

The latest, up-to-date edition.

Guide to on-site test methods for the analysis of waters
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

31-12-2008

Foreword
Section 1: General
1.1 Scope
1.2 Normative references
1.3 Terms and definitions
1.4 Information on MCERTS performance standards and
     test procedures for water test-kits
Section 2: Physical and chemical test methods: general
           information
2.1 Health and safety
2.2 Training, supervision and associated needs
2.3 Test facilities
2.4 Sampling, sampling preservation and sample pre-treatment
     considerations
2.5 Selection and application of test methods
2.6 Apparatus and equipment
2.7 Reagents
Section 3: Quality assurance and quality control (QA/QC)
3.1 Introduction
3.2 Causes of "unfit-for-purpose" results
3.3 Confidence interval considerations
3.4 Method validation (assessing method performance
     characteristics)
3.5 Routine quality control
3.6 Target test-kit requirements
3.7 Concentration ranges of methods
3.8 Interferences
Section 4: Titrimetric methods for use in a designated
           room/area testing facility
4.1 Determination of alkalinity
4.2 Determination of calcium and total hardness
4.3 Determination of chloride
4.4 Determination of free carbon dioxide
4.5 Determination of nitrite
4.6 Determination of sulfate
4.7 Determination of sulfite
4.8 Determination of zinc
Section 5: Instrumental methods
5.1 Determination of dissolved oxygen
5.2 Determination of electrical conductivity
5.3 Determination of pH
5.4 Determination of total dissolved solids
5.5 Determination of turbidity
5.6 Ion selective electrodes (ISEs)
Section 6: Some designated room/area testing facility methods
6.1 General
6.2 Determination of oxidized nitrogen
6.3 Determination of biological oxygen demand
6.4 Chemical oxidation demand with dichromate
6.5 Chemical oxidation with manganese(III)
6.6 Chemical oxidation with permanganate
6.7 Total organic carbon
6.8 Total nitrogen
6.9 Determination of metals
6.10 Determination of organic compounds
Annexes
Annex A (informative) - Guidance on training, supervision and
        associated needs
Annex B (informative) - Example of a documented test-kit method
        and associated sampling protocol for a colorimetric
        method
Annex C (informative) - Typical expected result confidence
        intervals from a given QC solution, from a range of
        test-kits from two manufacturers
Annex D (informative) - An example of target test-kit requirements
        for a COD test-kit used in a designated room/area testing
        facility
Annex E (informative) - An example of target test-kit requirements
        for a free and total chlorine test-kit used on-site at
        the sampling location
Annex F (informative) - An example of routine QA/QC documentation
        for a COD test
Annex G (informative) - An example of routine QA/QC documentation
        for a free and total chlorine test
Annex H (informative) - An example of a typical Shewhart control
        chart and a blank Shewhart control chart
Annex I (informative) - Test-kit methods overview
Annex J (informative) - Summary of test-kits
Annex K (informative) - Indication of availability of visual test
        sticks for semi-quantitative determinations
Bibliography

Explains information and guidance on test methods for the analysis of industrial and other waters, which are applicable outside of a conventional laboratory as either in situ on-site tests; or the use of a close suitable designated room/area testing facility.

COMMENTARY ON 1.1. Emergency screening analysis for major pollution incidents is not covered. Information on this is available via the US EPA which has set up an Environmental Technology Verification (ETV) Programme [1] and published a series of verification reports developed for each verified technology. The reports contain the performance verification test results and meet the ETV programme’s stringent quality assurance and peer review requirements for a wide range of advanced monitoring systems for water analysis mainly directed to emergency incidents. Further information on rapid analytical response issues in emergency situations is available (Thompson and O’Neill, 2006 [2] and Thompson, 2009 [3]). This British Standard describes information and guidance on test methods for the analysis of industrial and other waters which are applicable outside of a conventional laboratory as either in situ on-site tests; or the use of a close suitable designated room/area testing facility. For some tests this could include dedicated space in a designated vehicle or caravan. These test methods can relate to compliance, water quality and process control purposes. No recommendation is given as to which test is applicable to a particular type of water, nor is it implied that in any given case all tests or any particular suite of tests are necessary. The selection of tests depends on local requirements and conditions. Samples requiring preservation for subsequent analysis are outside of the scope of this British Standard. Certain tests such as adsorbable organic halides (AOX), chemical oxygen demand (COD), total organic carbon (TOC) and total nitrogen need a suitable designated test room/area facility and are not considered suitable for testing outside of these designated areas. Sample stability is not considered to be a significant problem as most test-kit measurements are carried out with minimal delay. Most of the methods described in this standard can be applicable for use on clean or lightly polluted waters which might have undergone treatment or been modified for industrial use. Typically, the types of waters for which the tests are intended include the following: boiler waters; cooling waters; waters from hot water systems; waters from air conditioning systems; waters from industrial air washing systems; potable waters; ground waters; surface waters; process waters; and swimming pool waters. Certain more heavily polluted waters can be routinely tested for certain control purposes for specific determinands using the test methods cited in this British Standard. Such waters include: sewage works influents and effluents; selected industrial effluents. Emergency screening analysis for major pollution incidents is not covered (see commentary). The on-site methods outlined in this British Standard include titrimetric, colorimetric and instrumental analytical techniques and also includes consideration of commercial test-kits: their general principles and formats available. It is generally accepted that in the UK, the vast majority of on-site measurements are carried out using commercial test-kits rather than user-devised test-kit type methods following similar equivalent method procedures to those used in conventional laboratories. Also the designated room/area testing facility titrimetric methods described in Section4 of this standard might require staff with a greater degree of training than commercial test-kit titrimetric methods which can be readily used outside of these areas. These methods are less likely to be used by non-analysts than the more robust test-kit titrimetric methods. The technique used and principle of the designated room/area testing facility titrimetric method are described within each test method and each method is self-contained within a standard format. This British Standard does not apply to radioactivity, ecotoxicity (See Persoone et al., 2000 [4]) or microbiological testing. Spot tests are not covered (Jungris, 1997 [5]). Many of the relevant methods are suitable for analysis for the water framework directive (see Note and SWIFT 2003 [6]), water for human consumption (see Note) and for monitoring of discharges to water and sewer (EA, 2006 [7] and Dixon and Gardner, 1997 [8]). NOTE EC 2000 [9] is known as ‘the water framework directive; EC 1998 [10], The Water Supply (Water Quality) Regulations 2000 [11] and DWI [12] relate to water for human consumption.

Committee
EH/3/2
DevelopmentNote
Supersedes BS 1427(1993) & 08/30166603 DC. (01/2009)
DocumentType
Standard
Pages
128
PublisherName
British Standards Institution
Status
Current

BS 3285:1960 Methods of sampling superheated steam from steam generating units
BS EN 1899-1:1998 Water quality. Determination of biochemical oxygen demand after n days (BODn) Dilution and seeding method with allylthiourea addition
BS 2690-104:1983 Methods of testing water used in industry Silica: reactive, total and suspended
BS EN ISO 7027:2000 Water quality. Determination of turbidity
BS EN ISO 7887:2011 Water quality. Examination and determination of colour
BS EN ISO 3696:1995 Water for analytical laboratory use. Specification and test methods
BS 6070-6(1981) : LATEST METHODS OF SAMPLING AND TEST FOR SODIUM CARBONATE FOR INDUSTRIAL USE - DETERMINATION OF POURING DENSITY
BS 6068-6.10:1993 Water quality. Sampling Guidance on sampling of waste waters
BS ISO 15705:2002 Water quality. Determination of the chemical oxygen demand index (ST-COD). Small-scale sealed-tube method
BS 6068-2.26(1986) : 1986 AMD 10870 WATER QUALITY - PHYSICAL CHEMICAL AND BIOCHEMICAL METHODS - METHOD FOR DETERMINATION OF FREE CHLORINE AND TOTAL CHLORINE COLORIMETRIC METHOD USING N N DIETHYL 1,4 PHENYLENEDIAMINE FOR CONTROL PURPOSES
BS 2690-101:1984 Methods of testing water used in industry Dissolved oxygen
BS 6068-2.80(2002) : 2002 WATER QUALITY - DETERMINATION OF THE CHEMICAL OXYGEN DEMAND INDEX (ST-COD) - SMALL-SCALE SEALED-TUBE METHOD
BS 1704:1985 Specification for solid-stem general purpose thermometers
BS 6068-2.8:1984 Water quality. Physical, chemical and biochemical methods Determination of calcium content: EDTA titrimetric method
BS 6068-2.41:1993 Water quality. Physical, chemical and biochemical methods Determination of fluoride: electrochemical probe method for potable and lightly polluted water
BS EN 25814:1992 Method for determination of dissolved oxygen in water: electrochemical probe method
BS 6068-2.11:1984 Water quality. Physical, chemical and biochemical methods Determination of ammonium: manual spectrometric method
BS 6068-6.4:1987 Water quality. Sampling Guidance on sampling from lakes, natural and man-made
BS 6068-1.9:1998 Water quality. Glossary Alphabetical list and subject index
BS 6068-6.9:1993 Water quality. Sampling Guidance on sampling from marine waters
BS 6068-2.34:1988 Water quality. Physical, chemical and biochemical methods Method for the determination of the chemical oxygen demand
BS 3145:1978 Specification for laboratory pH meters
BS EN ISO 8467:1995 Water quality. Determination of permanganate index
BS EN 1899-2:1998 Water quality. Determination of biochemical oxygen demand after n days (BODn) Method for undiluted samples
BS ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results General principles and definitions
ISO 9297:1989 Water quality Determination of chloride Silver nitrate titration with chromate indicator (Mohr's method)
BS EN 27888:1993 Water quality. Method for the determination of electrical conductivity
BS 6068-6.11:1993 Water quality. Sampling Guidance on sampling of groundwaters
BS 6068-2.31:1987 Water quality. Physical, chemical and biochemical methods Method for determination of manganese: formaldoxime spectrometric method
ASTM D 888 : 2012-05 TEST METHODS FOR DISSOLVED OXYGEN IN WATER
BS EN ISO/IEC 17025:2005 General requirements for the competence of testing and calibration laboratories
BS 6068-2.63(1998) : 1998 WATER QUALITY - DETERMINATION OF BIOCHEMICAL OXYGEN DEMAND AFTER N DAYS (BODN) - PART 1: DILUTION AND SEEDING METHOD WITH ALLYLTHIOUREA ADDITION
ASTM D 5463 : 2013-03 GUIDE FOR USE OF TEST KITS TO MEASURE INORGANIC CONSTITUENTS IN WATER
BS ISO 17381:2003 Water quality. Selection and application of ready-to-use test kit methods in water analysis
ISO 10359-1:1992 Water quality — Determination of fluoride — Part 1: Electrochemical probe method for potable and lightly polluted water
ISO 8466-2:2001 Water quality — Calibration and evaluation of analytical methods and estimation of performance characteristics — Part 2: Calibration strategy for non-linear second-order calibration functions
BS 6068-6.8:1993 Water quality. Sampling Guidance on sampling of wet deposition
BS 2690-109:1984 Methods of testing water used in industry Alkalinity, acidity, pH value and carbon dioxide
ISO 7888:1985 Water quality — Determination of electrical conductivity
DD ENV ISO 13530:1999 Water quality. Guide to analytical quality control for water analysis
ISO 8466-1:1990 Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function
BS 6068-2.9:1984 Water quality. Physical, chemical and biochemical methods Determination of the sum of calcium and magnesium: EDTA titrimetric method
BS 6068-2.2:1983 Water quality. Physical, chemical and biochemical methods Determination of iron: 1,10-phenanthroline photometric method
BS 2586:1979 Specification for glass and reference electrodes for the measurement of pH
BS 6068-6.14:1998 Water quality. Sampling Guidance on quality assurance of environmental water sampling and handling
BS 6068-2.17:1986 Water quality. Physical, chemical and biochemical methods Methods for determination of total cyanide
BS 2690-102:1979 Methods of testing water used in industry Hydrazine: spectrophotometric method (4-dimethylaminobenzaldehyde)
BS 6068-2.64(1998) : 1998 WATER QUALITY - DETERMINATION OF BIOCHEMICAL OXYGEN DEMAND AFTER N DAYS (BODN) - PART 2: METHOD FOR UNDILUTED SAMPLES
BS 6068-6.7:1994 Water quality. Sampling Guidance on sampling of water and steam in boiler plants
BS 6068-2.37:1990 Water quality. Physical, chemical and biochemical methods Method for the determination of chloride via a silver nitrate titration with chromate indicator (Mohr\'s method)
BS 2690-106:1979 Methods of testing water used in industry Reactive aluminium: spectrophotometric method (catechol violet)
BS EN ISO 5667-3:2012 Water quality. Sampling Preservation and handling of water samples

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