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BS 4427-11:1983

Current

Current

The latest, up-to-date edition.

Methods of test for sodium tripolyphosphate (pentasodium triphosphate) and sodium pyrophosphate (tetrasodium pyrophosphate) for industrial use Separation by column chromatography and determination of the different phosphate forms

Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

28-02-1983

Foreword
Cooperating organizations
Method
1 Scope
2 Principle
3 Reagents
4 Apparatus
5 Procedure
6 Expression of results
7 Test report
Appendix
A Determination of phosphorus (V) oxide in the eluates
   obtained by chromatographic separation of a column
Table
1 Concentrations of standard matching solutions and
   corresponding optical path lengths of cells
Figures
1 Ion-exchange column with dropping funnel
2 Ion-exchange colume with typical syphon device
3 Typical graph obtained during the determination of
   the elution conditions

Determination of ortho-, pyro- and tripolyphosphates, and higher condensed phosphate forms, in the absence of $7Itetra$7R- and $7Ipenta$7R-metaphosphates.

This Part of BS 4427 describes a method for the separation and the determination of the different phosphate forms in sodium tripolyphosphate (pentasodium triphosphate) and sodium pyrophosphate (tetrasodium diphosphate) for industrial use.

The procedure specified allows the selective determinations of orthophosphate (Na2HPO4), of pyrophosphate (Na4P2O7) and of tripolyphosphate (Na5P3O10), and also the evaluation of the total content of more condensed forms of phosphates in the absence of tetrametaphosphates and pentametaphosphates.

NOTE 1 In practice, tetrametaphosphates and pentametaphosphates are not usually present in commercial tripolyphosphates and pyrophosphates.

NOTE 2 Although the procedure can separate orthophosphate, its determination is not possible if the content is lower than 0.1 % (m/m); in this case its determination should be carried out by the method specified in BS 4427-8.

NOTE 3 The titles of the publications referred to in this Part of this British Standard are listed on the inside back cover.

Committee
CII/34
DevelopmentNote
Supersedes 82/52542 DC. (08/2005) Reviewed and confirmed by BSI, December 2011. (11/2011)
DocumentType
Standard
Pages
14
PublisherName
British Standards Institution
Status
Current

BS 4427-10:1976 Methods of test for sodium tripolyphosphate (pentasodium triphosphate) and sodium pyrophosphate (tetrasodium pyrophosphate) for industrial use Determination of total phosphorus (V) oxide content: quinoline phosphomolybdate gravimetric method

BS 4427-10:1976 Methods of test for sodium tripolyphosphate (pentasodium triphosphate) and sodium pyrophosphate (tetrasodium pyrophosphate) for industrial use Determination of total phosphorus (V) oxide content: quinoline phosphomolybdate gravimetric method
BS 3978:1966 Specification for water for laboratory use
BS 4427-8:1974 Methods of test for sodium tripolyphosphate (pentasodium triphosphate) and sodium pyrophosphate (tetrasodium pyrophosphate) for industrial use Determination of orthophosphate content

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