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BS EN ISO 6145-11:2008

Current
Current

The latest, up-to-date edition.

Gas analysis. Preparation of calibration gas mixtures using dynamic volumetric methods Electrochemical generation
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

30-06-2009

Foreword
Introduction
1 Scope
2 Normative references
3 Procedure
  3.1 Principle
  3.2 Complementary gas
  3.3 Electrolytic systems for gas generation
  3.4 Apparatus
      3.4.1 Cell construction
      3.4.2 Current supply and gas flow control
  3.5 Gas mixture preparation
      3.5.1 Complementary gas
      3.5.2 Voltage supply
      3.5.3 Calculation of gas mixture content
4 Uncertainty evaluation
  4.1 Introduction
  4.2 Sources of uncertainty
      4.2.1 Complementary gas flow
      4.2.2 Gas generation
      4.2.3 Absorption of generated gas in the cell
            electrolyte
      4.2.4 Effect of moisture content
      4.2.5 Effect of temperature
      4.2.6 Purity of electrolytic chemicals
      4.2.7 Impurities in complementary gas
  4.3 Uncertainty of volume fraction
5 Electrochemical cell design
Annex A (informative) - Example of a commercial
        electrochemical cell
Annex B (informative) - Schematics of electrolytic
        cells used for gas generation
Annex C (informative) - Schematic of electrical supply
        to gas generation cell
Annex D (informative) - Decomposition voltages of solutions
        between smooth platinum electrodes
Bibliography

Describes a method for the preparation of calibration gas mixtures by using electrochemical generation of a calibration component and introduction into a complementary gas flow.

Committee
PTI/15
DevelopmentNote
Renumbers and supersedes BS ISO 6145-11. 2008 version incorporates corrigendum to BS ISO 6145-11. Supersedes 04/30103207 DC. (06/2009)
DocumentType
Standard
Pages
26
PublisherName
British Standards Institution
Status
Current
Supersedes

Standards Relationship
ISO 6145-11:2005 Identical
EN ISO 6145-11:2008 Identical

ISO/IEC Guide 98:1993 Guide to the expression of uncertainty in measurement (GUM)
ISO 6145-7:2009 Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 7: Thermal mass-flow controllers
ISO 6143:2001 Gas analysis — Comparison methods for determining and checking the composition of calibration gas mixtures
ISO 7504:2015 Gas analysis Vocabulary
ISO 6145-1:2003 Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 1: Methods of calibration

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