Describes sampling and preparation of sampling media for dioxin-like polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in indoor air.

This part of ISO16000 specifies sampling and preparation of sampling media for dioxin-like polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in indoor air (see TableC.1). The method incorporates a sampling procedure that collects PCBs and PCDFs/PCDDs from air on a fine-particle filter backed up by a sorbent trap. The method cannot be used to separately determine gaseous PCBs and PCDFs/PCDDs and those that are particle-associated because some of the compounds will volatilize from the filter and be collected by the sorbent trap. This part of ISO16000 does not address analytical methods for PCBs PCDDs and PCDFs, which are included in ISO16000-14. (ISO16000-13 and ISO16000-14 are both parts of the overall measurement procedure for the determination of PCBs and PCDDs/PCDFs.)

Combined with the analytical procedures specified in ISO16000-14, which incorporate specific analyses by high-resolution gas chromatography combined with high-resolution mass spectrometry (HRGC/HRMS), this method is capable of detecting 0,2pg/m³ or lower concentrations of most PCBs and PCDFs/PCDDs. However, it may not be possible to detect all analytes at 0,2pg/m³ or lower, especially at lower sampling rates. To achieve adequate detection limits, no less than 50m³ of air should be sampled. For normal measurement tasks, sampling volumes up to 360m³ are employed (equivalent to a sampling period of 24h at 16m³/h or 7d at 2m³/h). The method has been validated for sampling periods up to seven days. With the use of larger sorbent traps, sampling volumes up to 1000m³ have been validated.

Sampling precision under normal conditions can be expected to be±25%or better and uncertainty±50%or better.

If the appropriate restrictions are applied, this method can be used for small rooms, for example children’s rooms as well as for offices.