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EN ISO 14362-3:2017

Current
Current

The latest, up-to-date edition.

Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene (ISO 14362-3:2017)
Published date

08-02-2017

European foreword
Foreword
1 Scope
2 Normative references
3 Terms and definition
4 General
5 Principle
6 Safety precautions
7 Reagents
8 Apparatus
9 Procedure
10 Evaluation
11 Test report
Annex A (informative) - Chromatographic analyses
Annex B (informative) - Calculation
Annex C (informative) - Reliability of the method
Annex D (informative) - Assessment guide -
        Interpretation of analytical results

Azo colorants that are able to form 4-aminoazobenzene, generate under the conditions of ISO 14362-1, the amines aniline and 1,4-phenylenediamine. The presence of these 4-aminoazobenzene colorants cannot be reliably ascertained without additional information (e.g. the chemical structure of the colorant used) or without a special procedure.ISO 14362-3:2017 is supplementary to ISO 14362-1 and describes a special procedure to detect the use, in commodities, of certain azo colorants, which may release 4-aminoazobenzene, and that are- accessible to reducing agent without extraction, particularly concerning textiles made of cellulose and protein fibres (e.g. cotton, viscose, wool, silk), and- accessible by extracting the fibres (e.g. polyester or imitation leather).For certain fibre blends, in 9.3 and 9.4 (with and without extraction) may need to be applied.The procedure also detects 4-aminoazobenzene (Solvent Yellow 1), which is already available as free amine in commodities without reducing pre-treatment.The use of certain azo colorants, which may release, by reductive cleavage of their azo group(s), one or more of the other aromatic amines listed in the Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) as regards Annex XVII, except 4-aminoazobenzene, cannot be determined quantitatively with this method.

Committee
CEN/TC 248
DevelopmentNote
Supersedes EN 14362-3. (02/2017)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
ISO 14362-1:2017 Textiles — Methods for determination of certain aromatic amines derived from azo colorants — Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres

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