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EN ISO 15512:2016

Withdrawn
Withdrawn

A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

View Superseded by
withdrawn

A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

Plastics - Determination of water content (ISO 15512:2016)
Withdrawn date

31-05-2017

Published date

09-11-2016

European foreword
Foreword
Introduction
1 Scope
2 Normative references
3 Method A - Extraction with anhydrous
  methanol
4 Method B1 - Water vaporization using
  a heating tube oven
5 Method B2 - Water vaporization using
  a heated sample vial
6 Method C - Manometric method
7 Test report
Annex A (informative) - Alternative sample preparation
        methods and titration methods
Annex B (informative) - Selection of the optimum heating
        temperature for the water content determination
Annex C (normative) - Determination of the water
        content of a water standard
Bibliography

1.1 ISO 15512:2016 specifies methods for the determination of the water content of plastics in the form of powder, granules, and finished articles. These methods do not test for water absorption (kinetics and equilibrium) of plastics as measured by ISO 62.Method A is suitable for the determination of water content as low as 0,1 % with an accuracy of 0,1 %. Method B and Method C are suitable for the determination of water content as low as 0,01 % with an accuracy of 0,01 %.Water content is an important parameter for processing materials and has to remain below the level specified in the appropriate material standard.1.2 Four alternative methods are specified in this International Standard.? Method A is an extraction method using anhydrous methanol followed by a Karl Fischer titration of the extracted water. It can be used for all plastics and is applicable to granules smaller than 4 mm × 4 mm × 3 mm. The method can also be used for, e.g. prepolymer materials in the form of a powder that are insoluble in methanol.? Method B1 is a vaporization method using a tube oven. The water contained in the test portion is vaporized and carried to the titration cell by a dry air or nitrogen carrier gas, followed by a Karl Fischer titration of the collected water. It can be used for all plastics and is applicable to granules smaller than 4 mm × 4 mm × 3 mm.? Method B2 is a vaporization method using a heated sample vial. The water contained in the test portion is vaporized and carried to the titration cell by a dry air or nitrogen carrier gas, followed by a Karl Fischer titration of the collected water. It can be used for all plastics and is applicable to granules smaller than 4 mm × 4 mm × 3 mm.? Method C is a manometric method. The water content is determined from the increase in pressure, which results when the water is evaporated under a vacuum. This method is not applicable to plastic samples containing volatile compounds, other than water, in amounts contributing significantly to the vapour pressure at room temperature. Checks for the presence of large amounts of volatile compounds are to be carried out periodically, for example by gas chromatography. Such checks are particularly required for new types or grades of material.

Committee
CEN/TC 249
DevelopmentNote
Supersedes EN ISO 960. (01/2004) Supersedes PREN ISO 15512. (09/2014)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Withdrawn
SupersededBy
Supersedes

EN 1555-1:2010 Plastics piping systems for the supply of gaseous fuels - Polyethylene (PE) - Part 1: General
UNI EN 1555-1 : 2011 PLASTICS PIPING SYSTEMS FOR THE SUPPLY OF GASEOUS FUELS - POLYETHYLENE (PE) - PART 1: GENERAL
NF EN 1555-1 : 2010 PLASTICS PIPING SYSTEMS FOR THE SUPPLY OF GASEOUS FUELS - POLYETHYLENE (PE) - PART 1: GENERAL
DIN EN 13341:2011-04 Static thermoplastic tanks for above ground storage of domestic heating oils, kerosene and diesel fuels - Blow moulded and rotationally moulded polyethylene tanks and rotationally moulded tanks made of anionically polymerized polyamide 6 - Requirements and test methods (includes Amendment A1:2011)
DIN EN 12201-1:2011-11 Plastics piping systems for water supply, and for drainage and sewerage under pressure - Polyethylene (PE) - Part 1: General
UNE-EN 16245-2:2014 Fibre-reinforced plastic composites - Declaration of raw material characteristics - Part 2: Specific requirements for resin, curing systems, additives and modifiers
BS EN 1555-1:2010 Plastics piping systems for the supply of gaseous fuels. Polyethylene (PE) General
EN 12201-1:2011 Plastics piping systems for water supply, and for drainage and sewerage under pressure - Polyethylene (PE) - Part 1: General
EN 13341:2005+A1:2011 Static thermoplastic tanks for above ground storage of domestic heating oils, kerosene and diesel fuels - Blow moulded and rotationally moulded polyethylene tanks and rotationally moulded tanks made of anionically polymerized polyamide 6 - Requirements and test methods
10/30212144 DC : 0 BS EN 12201-1 - PLASTICS PIPING SYSTEMS FOR WATER SUPPLY, AND FOR DRAINAGE AND SEWERAGE UNDER PRESSURE - POLYETHYLENE (PE) - PART 1: GENERAL
11/30239977 DC : 0 BS EN 16245-2 - FIBRE-REINFORCED PLASTIC COMPOSITES - DECLARATION OF RAW MATERIAL CHARACTERISTICS - PART 2: ADDITIONAL REQUIREMENTS FOR RESINS, CURING SYSTEMS, ADDITIVES AND MODIFIERS
DIN EN 16245-2:2013-08 Fibre-reinforced plastic composites - Declaration of raw material characteristics - Part 2: Specific requirements for resin, curing systems, additives and modifiers
DIN EN 14427:2014-09 LPG equipment and accessories - Transportable refillable fully wrapped composite cylinders for LPG - Design and construction
I.S. EN 12201-1:2011 PLASTICS PIPING SYSTEMS FOR WATER SUPPLY, AND FOR DRAINAGE AND SEWERAGE UNDER PRESSURE - POLYETHYLENE (PE) - PART 1: GENERAL
I.S. EN 1555-1:2010-2015 PLASTICS PIPING SYSTEMS FOR THE SUPPLY OF GASEOUS FUELS - POLYETHYLENE (PE) - PART 1: GENERAL
I.S. EN 14427:2014 LPG EQUIPMENT AND ACCESSORIES - TRANSPORTABLE REFILLABLE FULLY WRAPPED COMPOSITE CYLINDERS FOR LPG - DESIGN AND CONSTRUCTION
I.S. EN 13341:2005 STATIC THERMOPLASTIC TANKS FOR ABOVE GROUND STORAGE OF DOMESTIC HEATING OILS, KEROSENE AND DIESEL FUELS - BLOW MOULDED AND ROTATIONALLY MOULDED POLYETHYLENE TANKS AND ROTATIONALLY MOULDED TANKS MADE OF ANIONICALLY POLYMERIZED POLYAMIDE 6 - REQUIREMENTS AND TEST METHODS
VDI 3822 Blatt 2.1.8:2012-01 Failure analysis - Defects of thermoplastic products made of plastics caused by weather-induced stress
UNE-EN 15348:2015 Plastics - Recycled plastics - Characterization of poly(ethylene terephthalate) (PET) recyclates
I.S. EN 16245-2:2013 FIBRE-REINFORCED PLASTIC COMPOSITES - DECLARATION OF RAW MATERIAL CHARACTERISTICS - PART 2: SPECIFIC REQUIREMENTS FOR RESIN, CURING SYSTEMS, ADDITIVES AND MODIFIERS
DIN EN 1555-1:2010-12 Plastics piping systems for the supply of gaseous fuels - Polyethylene (PE) - Part 1: General
BS EN 12201-1:2011 Plastics piping systems for water supply, and for drainage and sewerage under pressure. Polyethylene (PE) General
DIN EN 14427 E : 2014 LPG EQUIPMENT AND ACCESSORIES - TRANSPORTABLE REFILLABLE FULLY WRAPPED COMPOSITE CYLINDERS FOR LPG - DESIGN AND CONSTRUCTION
EN 16245-2:2013 Fibre-reinforced plastic composites - Declaration of raw material characteristics - Part 2: Specific requirements for resin, curing systems, additives and modifiers
UNI EN 13341 : 2011 STATIC THERMOPLASTIC TANKS FOR ABOVE GROUND STORAGE OF DOMESTIC HEATING OILS, KEROSENE AND DIESEL FUELS - BLOW MOULDED AND ROTATIONALLY MOULDED POLYETHYLENE TANKS AND ROTATIONALLY MOULDED TANKS MADE OF ANIONICALLY POLYMERIZED POLYAMIDE 6 - REQUIREMENTS AND TEST METHODS
UNI EN 16245-2 : 2013 FIBRE-REINFORCED PLASTIC COMPOSITES - DECLARATION OF RAW MATERIAL CHARACTERISTICS - PART 2: SPECIFIC REQUIREMENTS FOR RESIN, CURING SYSTEMS, ADDITIVES AND MODIFIERS
UNI EN 12201-1 : 2012 PLASTICS PIPING SYSTEMS FOR WATER SUPPLY, AND FOR DRAINAGE AND SEWERAGE UNDER PRESSURE - POLYETHYLENE (PE) - PART 1: GENERAL
UNI EN 14427 : 2014 LPG EQUIPMENT AND ACCESSORIES - TRANSPORTABLE REFILLABLE FULLY WRAPPED COMPOSITE CYLINDERS FOR LPG - DESIGN AND CONSTRUCTION
DIN EN 16682 E : 2017 CONSERVATION OF CULTURAL HERITAGE - METHODS OF MEASUREMENT OF MOISTURE CONTENT, OR WATER CONTENT, IN MATERIALS CONSTITUTING IMMOVABLE CULTURAL HERITAGE
BS EN 16245-2:2013 Fibre-reinforced plastic composites. Declaration of raw material characteristics Specific requirements for resin, curing systems, additives and modifiers
BS EN 16682:2017 Conservation of cultural heritage. Methods of measurement of moisture content, or water content, in materials constituting immovable cultural heritage
DIN EN 15348:2015-01 PLASTICS - RECYCLED PLASTICS - CHARACTERIZATION OF POLY(ETHYLENE TEREPHTHALATE) (PET) RECYCLATES
BS EN 15348:2014 Plastics. Recycled plastics. Characterization of poly(ethylene terephthalate) (PET) recyclates
I.S. EN 16682:2017 CONSERVATION OF CULTURAL HERITAGE - METHODS OF MEASUREMENT OF MOISTURE CONTENT, OR WATER CONTENT, IN MATERIALS CONSTITUTING IMMOVABLE CULTURAL HERITAGE
BS EN 14427:2014 LPG equipment and accessories. Transportable refillable fully wrapped composite cylinders for LPG. Design and construction
UNE-EN 1555-1:2011 Plastics piping systems for the supply of gaseous fuels - Polyethylene (PE) - Part 1: General
UNE-EN 14427:2014 LPG equipment and accessories - Transportable refillable fully wrapped composite cylinders for LPG - Design and construction
BS EN 13341 : 2005 STATIC THERMOPLASTIC TANKS FOR ABOVE GROUND STORAGE OF DOMESTIC HEATING OILS, KEROSENE AND DIESEL FUELS - BLOW MOULDED AND ROTATIONALLY MOULDED POLYETHYLENE TANKS AND ROTATIONALLY MOULDED TANKS MADE OF ANIONICALLY POLYMERIZED POLYAMIDE 6 - REQUIREMENTS AND TEST METHODS
EN 14427:2014 LPG equipment and accessories - Transportable refillable fully wrapped composite cylinders for LPG - Design and construction
EN 16682:2017 Conservation of cultural heritage - Methods of measurement of moisture content, or water content, in materials constituting immovable cultural heritage
EN 15348:2014 Plastics - Recycled plastics - Characterization of poly(ethylene terephthalate) (PET) recyclates
DIN EN 15348 E : 2015 PLASTICS - RECYCLED PLASTICS - CHARACTERIZATION OF POLY(ETHYLENE TEREPHTHALATE) (PET) RECYCLATES
11/30229997 DC : 0 BS EN 14427 - LPG EQUIPMENT AND ACCESSORIES - TRANSPORTABLE REFILLABLE COMPOSITE CYLINDERS FOR LPG - DESIGN AND CONSTRUCTION
DIN EN 16682:2016-01 (Draft) CONSERVATION OF CULTURAL HERITAGE - METHODS OF MEASUREMENT OF MOISTURE CONTENT, OR WATER CONTENT, IN MATERIALS CONSTITUTING IMMOVABLE CULTURAL HERITAGE
I.S. EN 15348:2014 PLASTICS - RECYCLED PLASTICS - CHARACTERIZATION OF POLY(ETHYLENE TEREPHTHALATE) (PET) RECYCLATES
UNE-EN 12201-1:2012 Plastics piping systems for water supply, and for drainage and sewerage under pressure - Polyethylene (PE) - Part 1: General

ISO 1628-1:2009 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 1: General principles
ISO 1628-5:1998 Plastics — Determination of the viscosity of polymers in dilute solution using capillary viscometers — Part 5: Thermoplastic polyester (TP) homopolymers and copolymers
ISO 1628-6:1990 Plastics — Determination of viscosity number and limiting viscosity number — Part 6: Methyl methacrylate polymers
ISO 1628-3:2010 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 3: Polyethylenes and polypropylenes
ISO 307:2007 Plastics Polyamides Determination of viscosity number
ISO 62:2008 Plastics Determination of water absorption
ISO 1628-2:1998 Plastics Determination of the viscosity of polymers in dilute solution using capillary viscometers Part 2: Poly(vinyl chloride) resins
ISO 1628-4:1999 Plastics — Determination of the viscosity of polymers in dilute solution using capillary viscometers — Part 4: Polycarbonate (PC) moulding and extrusion materials
ISO 760:1978 Determination of water Karl Fischer method (General method)

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