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PD CEN/TS 15863:2012

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Characterisation of waste. Leaching behaviour test for basic characterisation. Dynamic monolithic leaching test with periodic leachant renewal, under fixed test conditions
Available format(s)

Hardcopy , PDF

Superseded date

30-04-2015

Language(s)

English

Published date

31-07-2012

Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Reagents
6 Equipment
7 Sample preparation
8 Procedure
9 Calculations
10 Documentation and test report
11 Test performance
Annex A (informative) - Identification of release
        mechanisms and use of test results
Annex B (informative) - Examples of data about
        the L/A ratio
Annex C (informative) - Process map for CEN/TS 15863
Bibliography

Pertains to regularly shaped test portions of monolithic wastes with minimum dimensions of 40 mm in all directions, that are assumed to maintain their integrity over a time frame relevant for the considered scenario.

This Technical Specification is applicable for determining the leaching behaviour of monolithic wastes under dynamic conditions. The test is performed under fixed experimental conditions in this document. This test is aimed at determining the release as a function of time of inorganic constituents from a monolithic waste, when it is put into contact with an aqueous solution (leachant).

This dynamic monolithic leaching test (DMLT) is a parameter specific test as specified in EN 12920 and is therefore not aimed at simulating real situations. The application of this test method alone is not sufficient for the determination of the detailed leaching behaviour of a monolithic waste under specified conditions.

In the framework of EN 12920 and in combination with additional chemical information, the test results are used to identify the leaching mechanisms and their relative importance. The intrinsic properties can be used to predict the release of constituents at a given time frame, in order to assess the leaching behaviour of monolithic waste materials, placed in different situations or scenarios (including disposal and recycling scenarios).

The test method applies to regularly shaped test portions of monolithic wastes with minimum dimensions of 40 mm in all directions, that are assumed to maintain their integrity over a time frame relevant for the considered scenario. The test method applies to test portions for which the geometric surface area can be determined with the help of simple geometric equations. The test method applies to low permeable monolithic materials.

NOTE 1 If, in order to comply with the requirements of regular shape, the test portion is prepared by cutting or coring, then new surfaces are exposed which can lead to change(s) in leaching properties. On the other hand if the test portion is prepared by moulding, the surface will be dependent to the type of mould and the conditions of storage. If the intention is to evaluate the behaviour of the material core, the specimen needs to be stored without any contact with air to avoid carbonation.

NOTE 2 For monolithic waste materials with a saturated hydraulic conductivity higher than 10-8 m/s water is likely to percolate through the monolith rather than flow around. In such cases relating the release to the geometric surface can lead to misinterpretation. A percolation test is then more appropriate (e.g. CEN/TS 14405).

This procedure may not be applicable to materials reacting with the leachant, leading for example to excessive gas emission or an excessive heat release.

This document has been developed to determine the release of mainly inorganic constituents from wastes. It does not take into account the particular characteristics of organic constituents, nor the consequences of microbiological processes in organic degradable wastes.

Committee
EH/4
DevelopmentNote
Supersedes 08/30185785 DC. (08/2012)
DocumentType
Standard
Pages
32
PublisherName
British Standards Institution
Status
Superseded
SupersededBy
Supersedes

Standards Relationship
CEN/TS 15863:2012 Identical

ANS 16.1 : 2003(R2008) MEASUREMENT OF THE LEACHABILITY OF SOLIDIFIED LOW-LEVEL RADIOACTIVE WASTES BY A SHORT-TERM TEST PROCEDURE
CEN/TS 14429:2005 Characterization of waste - Leaching behaviour tests - Influence of pH on leaching with initial acid/base addition
NEN 7345 : 1995 LEACHING CHARACTERISTICS OF SOLID EARTHY AND STONY BUILDING AND WASTE MATERIALS - LEACHING TESTS - DETERMINATION OF THE LEACHING OF INORGANIC COMPONENTS FROM BUILDINGS AND MONOLITIC WASTE MATERIALS WITH THE DIFFUSION TEST
CEN/TS 14997 : 2006 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - INFLUENCE OF PH ON LEACHING WITH CONTINUOUS PH-CONTROL
EN 14346:2006 CHARACTERIZATION OF WASTE - CALCULATION OF DRY MATTER BY DETERMINATION OF DRY RESIDUE OR WATER CONTENT
ISO 5667-3:2012 Water quality Sampling Part 3: Preservation and handling of water samples
CEN/TS 15864:2015 Characterization of waste - Leaching behaviour test for basic characterization - Dynamic monolithic leaching test with continuous leachant renewal under conditions relevant for specified scenario(s)
EN 12457-1:2002 Characterisation of waste - Leaching - Compliance test for leaching of granular waste materials and sludges - Part 1: One stage batch test at a liquid to solid ratio of 2 l/kg for materials with high solid content and with particle size below 4 mm (without or with size reduction)
EN 16192:2011 Characterization of waste - Analysis of eluates
EN ISO 5667-3:2012 Water quality - Sampling - Part 3: Preservation and handling of water samples (ISO 5667-3:2012)
ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
EN 12920:2006+A1:2008 Characterization of waste - Methodology for the determination of the leaching behaviour of waste under specified conditions
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
EN 15002:2015 Characterization of waste - Preparation of test portions from the laboratory sample
CEN/TS 14405 : 2004 CHARACTERIZATION OF WASTE - LEACHING BEHAVIOUR TESTS - UP-FLOW PERCOLATION TEST (UNDER SPECIFIED CONDITIONS)
CEN/TS 15862:2012 Characterisation of waste - Compliance leaching test - One stage batch leaching test for monoliths at fixed liquid to surface area ratio (L/A) for test portions with fixed minimum dimensions
EN 14899:2005 Characterization of waste - Sampling of waste materials - Framework for the preparation and application of a Sampling Plan

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