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CEN/TS 14793:2005

Withdrawn
Withdrawn

A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

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withdrawn

A Withdrawn Standard is one, which is removed from sale, and its unique number can no longer be used. The Standard can be withdrawn and not replaced, or it can be withdrawn and replaced by a Standard with a different number.

Stationary source emission - Intralaboratory validation procedure for an alternative method compared to a reference method
Withdrawn date

03-07-2023

Published date

03-09-2005

Introduction
1 Scope
2 Normative references
3 Terms and definitions
  3.1 General Vocabulary
  3.2 Symbols
4 Contents of the validation
  4.1 General
  4.2 Description of the alternative method
  4.3 Determination of performance characteristics
      4.3.1 General
      4.3.2 Manual method
      4.3.3 Automatic method
  4.4 Calculation of the overall uncertainty
  4.5 In field validation
      4.5.1 Coverage of in field validation
      4.5.2 Evaluation of repeatability and non systematic
            deviation in relation to the reference method
5 Summary of experiments performed
Annex A (informative) - Example of measurement of repeatability
        and trueness of Thorin method compared to Ion
        chromatography for SO[2] measurement in stack
Annex B (informative) - Statistical tables
  B.1 Distribution of the Student probability function
  B.2 Critical values for Grubbs test
Bibliography

The purpose of this technical specification is to specify a validation procedure to show if an Alternative Method (AM) can be used as an alternative to the Standard Reference Method (SRM), both implemented to determine the same measurand. This document has been drawn up for laboratories working in air pollution measurements (and consequently examples taken from this sector are included in the appendices).In particular, this Technical Specification provides the statistical tools and different criteria to evaluate the alternative method; this does not release the person responsible for this validation from bearing technical and analytical judgement on the evaluation of the different criteria.Three steps are described in the validation procedure:-description of the AM and setting of the field of equivalence (range and type of gas matrix);-determination of the performance characteristics of the AM and calculation of the overall uncertainty where appropriate and check of compliance of the maximum overall uncertainty allowed for the SRM;-check of repeatability and lack of systematic deviation of the AM in the field in comparison with the SRM for the type of matrix defined in the field of equivalence.NOTESome parts of the second step of the validation of the alternative method should be performed by a recognised test-house.If the AM fulfils the requirement of the procedure, then the laboratory that carried out the whole validation process is allowed to use it as a SRM in the field application where the equivalence has been demonstrated.However, if the validation process involves at least 4 different accredited laboratories performing simultaneously parallel measurements in the field, and if the AM passes with success all the tests of the procedure, then this method could be proposed to CEN, who can decide to consider this AM as a new reference method (ARM).The use of this procedure implies that a reference method has been defined by the regulator or i

Committee
CEN/TC 264
DocumentType
Technical Specification
PublisherName
Comite Europeen de Normalisation
Status
Withdrawn
SupersededBy

11/30239461 DC : 0 BS EN ISO 16911-1 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF VELOCITY AND VOLUMETRIC FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD
I.S. EN ISO 16911-1:2013 STATIONARY SOURCE EMISSIONS - MANUAL AND AUTOMATIC DETERMINATION OF VELOCITY AND VOLUME FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD (ISO 16911-1:2013)
CEN/TS 16429:2013 Stationary source emissions - Sampling and determination of hydrogen chloride content in ducts and stacks - Infrared analytical technique
I.S. EN 12619:2013 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
EN 12619:2013 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
CEN/TS 15674:2007 Air quality - Measurement of stationary source emissions - Guidelines for the elaboration of standardised methods
CEN/TS 15675:2007 Air quality - Measurement of stationary source emissions - Application of EN ISO/IEC 17025:2005 to periodic measurements
PREN 12619 : DRAFT 2011 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
11/30238654 DC : 0 BS EN 12619 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
S.R. CEN GUIDE 13:2008 VALIDATION OF ENVIRONMENTAL TEST METHODS
S.R. CEN TS 15675:2007 AIR QUALITY - MEASUREMENT OF STATIONARY SOURCE EMISSIONS - APPLICATION OF EN ISO/IEC 17025:2005 TO PERIODIC MEASUREMENTS
S.R. CEN/TS 15674:2007 AIR QUALITY - MEASUREMENT OF STATIONARY SOURCE EMISSIONS - GUIDELINES FOR THE ELABORATION OF STANDARDISED METHODS
DIN EN 12619:2013-04 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
DIN EN 15259 E : 2008 AIR QUALITY - MEASUREMENT OF STATIONARY SOURCE EMISSIONS - REQUIREMENTS FOR MEASUREMENT SECTIONS AND SITES AND FOR THE MEASUREMENT OBJECTIVE, PLAN AND REPORT
DIN EN 15259:2008-01 Air quality - Measurement of stationary source emissions - Requirements for measurement sections and sites and for the measurement objective, plan and report
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VDI 2447:2011-04 Emission control - Plants to the production and processing of acrylonitrile (AN)
VDI 3896:2015-10 Emission control - Preparation of biogas to natural gas quality
VDI 2293:2011-09 Emission control - Coal preparation plants including driers
VDI 2578:2017-05 Emission control - Glassworks
VDI 3951:2013-09 Overview on relevant regulations on the performance of emission measurements
VDI 2580:2014-02 Emission control - Production plants for carbon black
VDI 3455:2013-08 Emission control - High-volume car body painting plants
VDI 3898:2013-01 Emission control - Plants for dry mechanical, physio-chemical, thermal and biological soil treatment
VDI 4220:2011-04 Quality assurance - Requirements on bodies for the determination of air pollutants at stationary sources and in ambient air
VDI 2102 Blatt 2:2013-04 Emission control - Copper and copper alloy melting plants
11/30243100 DC : 0 BS EN 13649 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF INDIVIDUAL GASEOUS ORGANIC COMPOUNDS - ACTIVATED CARBON AND SOLVENT DESORPTION METHOD
PD CEN/TS 13649:2014 Stationary source emissions. Determination of the mass concentration of individual gaseous organic compounds. Sorptive sampling method followed by solvent extraction or thermal desorption
I.S. EN 1911:2010 STATIONARY SOURCE EMISSIONS - DETERMINATION OF MASS CONCENTRATION OF GASEOUS CHLORIDES EXPRESSED AS HCL - STANDARD REFERENCE METHOD
PD CEN/TS 16429:2013 Stationary source emissions. Sampling and determination of hydrogen chloride content in ducts and stacks. Infrared analytical technique
PREN 16510-1 : DRAFT 2013 RESIDENTIAL SOLID FUEL BURNING APPLIANCES - PART 1: GENERAL REQUIREMENTS AND TEST METHODS
DD CEN/TS 15674:2007 Air quality. Measurement of stationary source emissions. Guidelines for the elaboration of standardised methods
UNI EN 12619 : 2013 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF TOTAL GASEOUS ORGANIC CARBON - CONTINUOUS FLAME IONISATION DETECTOR METHOD
UNI EN ISO 16911-1 : 2013 STATIONARY SOURCE EMISSIONS - MANUAL AND AUTOMATIC DETERMINATION OF VELOCITY AND VOLUME FLOW RATE IN DUCTS - PART 1: MANUAL REFERENCE METHOD
DIN EN 1911:2010-12 Stationary source emissions - Determination of mass concentration of gaseous chlorides expressed as HCl - Standard reference method
UNI CEN/TS 16429 : 2013 STATIONARY SOURCE EMISSIONS - SAMPLING AND DETERMINATION OF HYDROGEN CHLORIDE CONTENT IN DUCTS AND STACKS - INFRARED ANALYTICAL TECHNIQUE
UNI EN 1911 : 2010 STATIONARY SOURCE EMISSIONS - DETERMINATION OF MASS CONCENTRATION OF GASEOUS CHLORIDES EXPRESSED AS HCL - STANDARD REFERENCE METHOD
PREN 13649 : DRAFT 2011 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF INDIVIDUAL GASEOUS ORGANIC COMPOUNDS - ACTIVATED CARBON AND SOLVENT DESORPTION METHOD
BS EN 1911:2010 Stationary source emissions. Determination of mass concentration of gaseous chlorides expressed as HCl. Standard reference method
BS EN ISO 16911-1:2013 Stationary source emissions. Manual and automatic determination of velocity and volume flow rate in ducts Manual reference method
S.R. CEN/TS 13649:2014 STATIONARY SOURCE EMISSIONS - DETERMINATION OF THE MASS CONCENTRATION OF INDIVIDUAL GASEOUS ORGANIC COMPOUNDS - SORPTIVE SAMPLING METHOD FOLLOWED BY SOLVENT EXTRACTION OR THERMAL DESORPTION
13/30271701 DC : 0 BS EN 16510-1 - RESIDENTIAL SOLID FUEL BURNING APPLIANCES - PART 1: GENERAL REQUIREMENTS AND TEST METHODS
BS EN 12619:2013 Stationary source emissions. Determination of the mass concentration of total gaseous organic carbon. Continuous flame ionisation detector method
UNE-EN 12619:2013 Stationary source emissions - Determination of the mass concentration of total gaseous organic carbon - Continuous flame ionisation detector method
ISO 16911-1:2013 Stationary source emissions — Manual and automatic determination of velocity and volume flow rate in ducts — Part 1: Manual reference method
UNE-EN ISO 16911-1:2013 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013)
EN 1911:2010 Stationary source emissions - Determination of mass concentration of gaseous chlorides expressed as HCl - Standard reference method
EN 15259:2007 Air quality - Measurement of stationary source emissions - Requirements for measurement sections and sites and for the measurement objective, plan and report
EN ISO 16911-1:2013 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013)
DD CEN/TS 15675:2007 Air quality. Measurement of stationary source emissions. Application of EN ISO/IEC 17025:2005 to periodic measurements
CEN Guide 13:2008 Validation of environmental test methods
DIN EN ISO 16911-1:2013-06 Stationary source emissions - Manual and automatic determination of velocity and volume flow rate in ducts - Part 1: Manual reference method (ISO 16911-1:2013); German version EN ISO 16911-1:2013
UNE-EN 1911:2011 Stationary source emissions - Determination of mass concentration of gaseous chlorides expressed as HCl - Standard reference method
08/30188440 DC : 0 BS EN 1911 - STATIONARY SOURCE EMISSIONS - DETERMINATION OF MASS CONCENTRATION OF GASEOUS CHLORIDES EXPRESSED AS HCL - STANDARD REFERENCE METHOD
S.R. CEN/TS 16429:2013 STATIONARY SOURCE EMISSIONS - SAMPLING AND DETERMINATION OF HYDROGEN CHLORIDE CONTENT IN DUCTS AND STACKS - INFRARED ANALYTICAL TECHNIQUE
BS EN 15259:2007 Air quality. Measurement of stationary source emissions. Requirements for measurement sections and sites and for the measurement objective, plan and report
CEN/TS 13649:2014 Stationary source emissions - Determination of the mass concentration of individual gaseous organic compounds - Sorptive sampling method followed by solvent extraction or thermal desorption

ISO 5725-1:1994 Accuracy (trueness and precision) of measurement methods and results — Part 1: General principles and definitions
ISO 11843-1:1997 Capability of detection Part 1: Terms and definitions
ISO 14956:2002 Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty
ISO 11095:1996 Linear calibration using reference materials
ISO/IEC Guide 99:2007 International vocabulary of metrology Basic and general concepts and associated terms (VIM)
EN ISO 14956 : 2002 AIR QUALITY - EVALUATION OF THE SUITABILITY OF A MEASUREMENT PROCEDURE BY COMPARISON WITH A REQUIRED MEASUREMENT UNCERTAINTY
ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ENV 13005 : DRAFT 1999 GUIDE TO THE EXPRESSION OF UNCERTAINTY IN MEASUREMENT

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