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EN 1601:2017

Current
Current

The latest, up-to-date edition.

Liquid petroleum products - Determination of organic oxygenate compounds and total organically bound oxygen content in unleaded petrol - Method by gas chromatography (O-FID)
Published date

08-09-2017

European foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Reagents and materials
5 Apparatus
6 Sampling
7 Procedure
8 Calculation
9 Procedure for the determination of a higher
   oxygenate compound content
10 Total organically bound oxygen content
11 Expression of results
12 Precision
13 Test report
Annex A (informative) - Guidance on the oxygen selective
        detection (O-FID) technique
Bibliography

This European Standard specifies a gas chromatographic method for the quantitative determination, in unleaded petrol having a final boiling point not greater than 220 °C, of individual organic oxygenate compounds in the range 0,17 % (m/m) to 15 % (m/m) in a direct analysis (without dilution), and total organically bound oxygen up to 3,9 % (m/m).For samples for which one of the oxygenate compounds content is higher than 15 % (m/m), a procedure with a dilution of the sample before the analysis is given.NOTE 1The conversion from percent mass to percent volume is done using the calculation mentioned in 8.3 and 9.5.3.NOTE 2Precision data are not available for an oxygenate compound content higher than 15 % (m/m); see Introduction.NOTE 3For the purposes of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent respectively the mass fraction, µ, respectively the volume fraction, φ.WARNING - The use of this European Standard can involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this European Standard to take appropriate measures to ensure the safety and health of personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this purpose.

DevelopmentNote
Supersedes PREN 1601. (08/2017)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Current
Supersedes

S.R. CEN/TR 15993:2018 AUTOMOTIVE FUELS - ETHANOL (E85) AUTOMOTIVE FUEL - BACKGROUND TO THE PARAMETERS REQUIRED AND THEIR RESPECTIVE LIMITS AND DETERMINATION
I.S. EN 14517:2004 LIQUID PETROLEUM PRODUCTS - DETERMINATION OF HYDROCARBON TYPES AND OXYGENATES IN PETROL - MULTIDIMENSIONAL GAS CHROMATOGRAPHY METHOD
BS EN ISO 22854:2016 Liquid petroleum products. Determination of hydrocarbon types and oxygenates in automotive-motor gasoline and in ethanol (E85) automotive fuel. Multidimensional gas chromatography method
DD CEN/TS 15293:2011 Automotive fuels. Ethanol (E85) automotive fuel. Requirements and test methods
BS ISO 8178-5:2008 Reciprocating internal combustion engines. Exhaust emission measurement Test fuels
I.S. EN 228:2017 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
BS EN 14517:2004 Methods of test for petroleum and its products. BS 2000-526: Liquid petroleum products. Determination of hydrocarbon types and oxygenates in petrol. Multidimensional gas chromatography method
DIN EN 228:2004-03 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
CEN/TR 15993:2018 Automotive fuels - Ethanol (E85) automotive fuel - Background to the parameters required and their respective limits and determination
09/30206692 DC : 0 BS EN 228 - AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
S.R. CEN TS 15293:2011 AUTOMOTIVE FUELS - ETHANOL (E85) AUTOMOTIVE FUEL - REQUIREMENTS AND TEST METHODS
PD CEN/TR 16514:2013 Automotive fuels. Unleaded petrol containing more than 3,7 % (m/m) oxygen. Roadmap, test methods, and requirements for E10+ petrol
09/30199323 DC : 0 BS EN 15293 - AUTOMOTIVE FUELS - ETHANOL (E85) AUTOMOTIVE FUEL REQUIREMENTS AND TEST METHODS
BS 2000-156(2007) : 2007 PETROLEUM PRODUCTS AND RELATED MATERIALS - DETERMINATION OF HYDROCARBON TYPES - FLUORESCENT INDICATOR ADSORPTION METHOD
13/30279896 DC : 0 BS ISO 8178-5 - RECIPROCATING INTERNAL COMBUSTION ENGINES - EXHAUST EMISSION MEASUREMENT - PART 5: TEST FUELS
I.S. EN ISO 22854:2016 LIQUID PETROLEUM PRODUCTS - DETERMINATION OF HYDROCARBON TYPES AND OXYGENATES IN AUTOMOTIVE-MOTOR GASOLINE AND IN ETHANOL (E85) AUTOMOTIVE FUEL - MULTIDIMENSIONAL GAS CHROMATOGRAPHY METHOD (ISO 22854:2016)
ISO 8178-5:2015 Reciprocating internal combustion engines Exhaust emission measurement Part 5: Test fuels
DIN EN 15553 E : 2007 PETROLEUM PRODUCTS AND RELATED MATERIALS - DETERMINATION OF HYDROCARBON TYPES - FLUORESCENT INDICATOR ADSORPTION METHOD
DIN EN 228:2017-08 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
PD CEN/TR 15993:2013 Automotive fuels. Ethanol (E85) automotive fuel. Background to the parameters required and their respective limits and determination
12/30263877 DC : 0 BS EN ISO 22854 - LIQUID PETROLEUM PRODUCTS - DETERMINATION OF HYDROCARBON TYPES AND OXYGENATES IN AUTOMOTIVE-MOTOR GASOLINE - MULTIDIMENSIONAL GAS CHROMATOGRAPHY METHOD
PREN 228 : DRAFT 2009 AUTOMOTIVE FUELS - UNLEADED PETROL - REQUIREMENTS AND TEST METHODS
EN ISO 22854:2016 LIQUID PETROLEUM PRODUCTS - DETERMINATION OF HYDROCARBON TYPES AND OXYGENATES IN AUTOMOTIVE-MOTOR GASOLINE AND IN ETHANOL (E85) AUTOMOTIVE FUEL - MULTIDIMENSIONAL GAS CHROMATOGRAPHY METHOD (ISO 22854:2016)
BS EN 15553:2007 Petroleum products and related materials. Determination of hydrocarbon types. Fluorescent indicator adsorption method
ISO 22854:2016 Liquid petroleum products Determination of hydrocarbon types and oxygenates in automotive-motor gasoline and in ethanol (E85) automotive fuel Multidimensional gas chromatography method
DIN EN 15553:2007-07 Petroleum products and related materials - Determination of hydrocarbon types - Fluorescent indicator adsorption method
EN 14517:2004 Liquid petroleum products - Determination of hydrocarbon types and oxygenates in petrol - Multidimensional gas chromatography method
EN 228:2012+A1:2017 Automotive fuels - Unleaded petrol - Requirements and test methods
UNE-EN ISO 22854:2016 Liquid petroleum products - Determination of hydrocarbon types and oxygenates in automotive-motor gasoline and in ethanol (E85) automotive fuel - Multidimensional gas chromatography method (ISO 22854:2016)
S.R. CEN/TR 16514:2013 AUTOMOTIVE FUELS - UNLEADED PETROL CONTAINING MORE THAN 3,7% (M/M) OXYGEN - ROADMAP, TEST METHODS, AND REQUIREMENTS FOR E10+ PETROL
I.S. CWA 15293:2005 AUTOMOTIVE FUELS - ETHANOL E85 - REQUIREMENTS AND TEST METHODS
I.S. EN 15553:2007 PETROLEUM PRODUCTS AND RELATED MATERIALS - DETERMINATION OF HYDROCARBON TYPES - FLUORESCENT INDICATOR ADSORPTION METHOD
CEN/TS 15293:2011 Automotive fuels - Ethanol (E85) automotive fuel - Requirements and test methods
EN 15553:2007 Petroleum products and related materials - Determination of hydrocarbon types - Fluorescent indicator adsorption method
DIN EN 14517:2004-12 METHODS OF TEST FOR PETROLEUM AND ITS PRODUCTS - BS 2000-256: LIQUID PETROLEUM PRODUCTS - DETERMINATION OF HYDROCARBON TYPES AND OXYGENATES IN PETROL - MULTIDIMENSIONAL GAS CHROMATOGRAPHY METHOD
CEN/TR 16514 : 2013 AUTOMOTIVE FUELS - UNLEADED PETROL CONTAINING MORE THAN 3,7% (M/M) OXYGEN - ROADMAP, TEST METHODS, AND REQUIREMENTS FOR E10+ PETROL
UNE-EN 228:2013 Automotive fuels - Unleaded petrol - Requirements and test methods

ISO 3171:1988 Petroleum liquids — Automatic pipeline sampling
EN 228:2012+A1:2017 Automotive fuels - Unleaded petrol - Requirements and test methods
ISO 3170:2004 Petroleum liquids — Manual sampling
ISO 3675:1998 Crude petroleum and liquid petroleum products Laboratory determination of density Hydrometer method
EN ISO 12185:1996 Crude petroleum and petroleum products - Determination of density - Oscillating U-tube method (ISO 12185:1996)
EN ISO 3675:1998 Crude petroleum and liquid petroleum products - Laboratory determination of density - Hydrometer method (ISO 3675:1998)
ISO 12185:1996 Crude petroleum and petroleum products — Determination of density — Oscillating U-tube method
ISO 3838:2004 Crude petroleum and liquid or solid petroleum products Determination of density or relative density Capillary-stoppered pyknometer and graduated bicapillary pyknometer methods
ISO 4259:2006 Petroleum products Determination and application of precision data in relation to methods of test
EN ISO 3170:2004 Petroleum liquids - Manual sampling (ISO 3170:2004)
EN ISO 3838:2004 Crude petroleum and liquid or solid petroleum products - Determination of density or relative density - Capillary-stoppered pyknometer and graduated bicapillary pyknometer methods (ISO 3838:2004)
EN ISO 3171:1999 Petroleum liquids - Automatic pipeline sampling (ISO 3171:1988)
EN ISO 4259:2006 Petroleum products - Determination and application of precision data in relation to methods of test (ISO 4259:2006)

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