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ASTM D 1319 : 2018

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
Available format(s)

Hardcopy , PDF

Superseded date

05-10-2023

Language(s)

English

Published date

12-06-2018

This test method covers the determination of hydrocarbon types over the concentration ranges from 5 % to 99 % by volume  aromatics, 0.3 % to 55 % by volume olefins, and 1 % to 95 % by volume  saturates in petroleum fractions that distill below 315 °C.

1.1This test method covers the determination of hydrocarbon types over the concentration ranges from 5 % to 99 % by volume  aromatics, 0.3 % to 55 % by volume olefins, and 1 % to 95 % by volume  saturates in petroleum fractions that distill below 315 °C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.

Note 1:For the determination of olefins below 0.3 % by volume, other test methods are available, such as Test Method D2710.

1.2This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and results are erratic.

1.3This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method D1319 and the distillation temperature T95, at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested according to Test Method D86.

1.3.1The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method D5769 and the distillation temperature T95 values, at which 95 % of the sample has evaporated, when tested according to Test Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).

1.4The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.

1.5This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13 % to 40 % by volume aromatics, 4 % to 33 % by volume olefins, and 45 % to 68 % by volume saturates.

1.6The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.

1.7WARNING—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use Caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.

1.8The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.9This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.

1.10This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 02
DocumentType
Test Method
Pages
8
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

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ASTM D 7589 : 2016 : EDT 1 Standard Test Method for Measurement of Effects of Automotive Engine Oils on Fuel Economy of Passenger Cars and Light-Duty Trucks in Sequence VID Spark Ignition Engine<rangeref></rangeref >
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ASTM D 6923 : 2018 Standard Test Method for Evaluation of Engine Oils in a High Speed, Single-Cylinder Diesel Engine—Caterpillar 1R Test Procedure
ASTM D 3244 : 2018 Standard Practice for Utilization of Test Data to Determine Conformance with Specifications
ASTM D 8074 : 2018 Standard Test Method for Evaluation of Diesel Engine Oils in DD13 Diesel Engine
ASTM D 7156 : 2017 Standard Test Method for Evaluation of Diesel Engine Oils in the T-11 Exhaust Gas Recirculation Diesel Engine
ASTM D 6730 : 2001 : R2016 Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100–Metre Capillary (with Precolumn) High-Resolution Gas Chromatography
ASTM D 1655 : 2019 Standard Specification for Aviation Turbine Fuels
ASTM D 5186 : 2019 Standard Test Method for Determination of the Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels By Supercritical Fluid Chromatography
ASTM D 6709 : 2015 : REV A Standard Test Method for Evaluation of Automotive Engine Oils in the Sequence VIII Spark-Ignition Engine (CLR Oil Test Engine)
ASTM D 5966 : 2013 Standard Test Method for Evaluation of Engine Oils for Roller Follower Wear in Light-Duty Diesel Engine (Withdrawn 2022)
ASTM D 3338/D3338M : 2009 : R2014 : EDT 2 Standard Test Method for Estimation of Net Heat of Combustion of Aviation Fuels
ASTM D 6591 : 2019 Standard Test Method for Determination of Aromatic Hydrocarbon Types in Middle Distillates—High Performance Liquid Chromatography Method with Refractive Index Detection
ASTM D 7223 : 2017 Standard Specification for Aviation Certification Turbine Fuel
ASTM D 6681 : 2017 Standard Test Method for Evaluation of Engine Oils in a High Speed, Single-Cylinder Diesel Engine—Caterpillar 1P Test Procedure
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ASTM D 8048 : 2019 Standard Test Method for Evaluation of Diesel Engine Oils in T-13 Diesel Engine
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ASTM D 2425 : 2019 Standard Test Method for Hydrocarbon Types in Middle Distillates by Mass Spectrometry
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ASTM D 7467 : 2019 Standard Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20)
ASTM D 5134 : 2013 : R2017 Standard Test Method for Detailed Analysis of Petroleum Naphthas through n-Nonane by Capillary Gas Chromatography
ASTM D 8111 : 2019 Standard Test Method for Evaluation of Automotive Engine Oils in the Sequence IIIH, Spark-Ignition Engine
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ASTM D 7566 : 2019 Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons
ASTM D 6837 : 2013 Standard Test Method for Measurement of Effects of Automotive Engine Oils on Fuel Economy of Passenger Cars and Light-Duty Trucks in Sequence VIB Spark Ignition Engine<rangeref></rangeref > (Withdrawn 2022)
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ASTM D 8047 : 2018 Standard Test Method for Evaluation of Engine Oil Aeration Resistance in a Caterpillar C13 Direct-Injected Turbocharged Automotive Diesel Engine
ASTM D 6894 : 2013 Standard Test Method for Evaluation of Aeration Resistance of Engine Oils in Direct-Injected Turbocharged Automotive Diesel Engine (Withdrawn 2022)
ASTM D 7422 : 2017 : REV A Standard Test Method for Evaluation of Diesel Engine Oils in T-12 Exhaust Gas Recirculation Diesel Engine
ASTM D 4054 : 2019 Standard Practice for Evaluation of New Aviation Turbine Fuels and Fuel Additives
ASTM D 6550 : 2015 Standard Test Method for Determination of Olefin Content of Gasolines by Supercritical-Fluid Chromatography
ASTM D 3343 : 2016 Standard Test Method for Estimation of Hydrogen Content of Aviation Fuels
ASTM D 6750 : 2019 Standard Test Methods for Evaluation of Engine Oils in a High-Speed, Single-Cylinder Diesel Engine—1K Procedure (0.4 % Fuel Sulfur) and 1N Procedure (0.04 % Fuel Sulfur)
ASTM D 5967 : 2017 Standard Test Method for Evaluation of Diesel Engine Oils in T-8 Diesel Engine
ASTM D 3734 : 2005 : R2018 Standard Specification for High-Flash Aromatic Naphthas
ASTM D 7589 : 2016 Standard Test Method for Measurement of Effects of Automotive Engine Oils on Fuel Economy of Passenger Cars and Light-Duty Trucks in Sequence VID Spark Ignition Engine<rangeref></rangeref >
ASTM D 7583 : 2016 Standard Test Method for John Deere Coolant Cavitation Test

ASTM D 4057 : 2019 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 1655 : 2008 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 5769 : 1998 Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
ASTM D 6708 : 2018 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2015 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2013 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2011 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 5769 : 2010 Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
ASTM D 1655 : 2012 Standard Specification for Aviation Turbine Fuels
ASTM D 4815 : 2015 : REV B Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<inf>1</inf> to C<inf>4</inf> Alcohols in Gasoline by Gas Chromatography
ASTM D 1655 : 2006 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2006 : REV C Standard Specification for Aviation Turbine Fuels
ASTM D 6708 : 2007 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2018 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2005 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2017 Standard Specification for Aviation Turbine Fuels
ASTM D 4057 : 2012 : R2018 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 3663 : 2003 : R2008 Standard Test Method for Surface Area of Catalysts and Catalyst Carriers
ASTM D 5599 : 2000 : R2010 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 1655 : 2014 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 5769 : 2010 : R2015 Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
ASTM D 1655 : 2001 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2011 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 6708 : 2016 : REV B Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2006 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2006 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 4057 : 1981 : EDT 2 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 5599 : 2018 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 1655 : 2015 : REV D Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2008 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2002 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2006 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2016 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2010 Standard Specification for Aviation Turbine Fuels
ASTM D 6708 : 2004 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2017 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 2710 : 2009 Standard Test Method for Bromine Index of Petroleum Hydrocarbons by Electrometric Titration
ASTM D 1655 : 2000 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 6708 : 2019 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2016 : REV A Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 6708 : 2008 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2015 : REV C Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2015 Standard Specification for Aviation Turbine Fuels
ASTM D 4057 : 2006 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 1655 : 2007 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2015 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 4057 : 2012 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4815 : 1999 : EDT 1 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, <I>tertiary</I>-Amyl Alcohol and C<sub>1</sub> to C<sub>4</sub> Alcohols in Gasoline by Gas Chromatography
ASTM D 1655 : 2012 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 3663 : 2003 : R2015 Standard Test Method for Surface Area of Catalysts and Catalyst Carriers
ASTM D 6708 : 2001 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 4815 : 2009 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<sub>1</sub> to C<sub>4</sub> Alcohols in Gasoline by Gas Chromatography
ASTM D 1655 : 2014 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2015 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 1985 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2016 : REV C Standard Specification for Aviation Turbine Fuels
ASTM D 3663 : 1999 Standard Test Method for Surface Area of Catalysts and Catalyst Carriers
ASTM D 4815 : 2015 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<inf>1</inf> to C<inf>4</inf> Alcohols in Gasoline by Gas Chromatography
ASTM D 4815 : 2004 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<sub>1</sub> to C<sub>4</sub> Alcohols in Gasoline by Gas Chromatography
ASTM D 4815 : 1999 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, <I>tertiary</I>-Amyl Alcohol and C<sub>1</sub> to C<sub>4</sub> Alcohols in Gasoline by Gas Chromatography
ASTM D 6708 : 2001 : EDT 1 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2004 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 6708 : 2005 Standard Practice for Statistical Assessment and Improvement of the Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 5599 : 2015 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 5599 : 2017 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 6708 : 2013 : EDT 1 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2016 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 4815 : 2013 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<inf>1</inf> to C<inf>4</inf> Alcohols in Gasoline by Gas Chromatography
ASTM D 6708 : 2016 Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material
ASTM D 1655 : 2004 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2014 : REV C Standard Specification for Aviation Turbine Fuels
ASTM D 5599 : 2000 : R2005 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 1655 : 2016 : REV B Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2007 : EDT 1 Standard Specification for Aviation Turbine Fuels
ASTM D 4815 : 2003 Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<sub>1</sub> to C<sub>4</sub> Alcohols in Gasoline by Gas Chromatography
ASTM D 1655 : 2000 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2013 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2015 : REV D : EDT 1 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2019 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2006 : REV D Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2003 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2014 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2003 Standard Specification for Aviation Turbine Fuels
ASTM D 5769 : 2004 Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
ASTM D 1655 : 2009 Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2011 Standard Specification for Aviation Turbine Fuels
ASTM D 3663 : 2003 Standard Test Method for Surface Area of Catalysts and Catalyst Carriers
ASTM D 5599 : 2000 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
ASTM D 2710 : 2009 : R2013 Standard Test Method for Bromine Index of Petroleum Hydrocarbons by Electrometric Titration
ASTM D 1655 : 2009 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 1655 : 2018 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 4057 : 1995 : R2000 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 1655 : 2018 Standard Specification for Aviation Turbine Fuels
ASTM D 4815 : 2015 : REV A Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C<inf>1</inf> to C<inf>4</inf> Alcohols in Gasoline by Gas Chromatography
ASTM D 4057 : 2006 : R2011 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 1655 : 2013 : REV A Standard Specification for Aviation Turbine Fuels
ASTM D 5769 : 2015 Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry
ASTM D 2710 : 1999 Standard Test Method for Bromine Index of Petroleum Hydrocarbons by Electrometric Titration

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