ASTM D 5542 : 2016
Current
The latest, up-to-date edition.
Hardcopy , PDF
English
06-01-2016
These test methods cover the determination of trace (μg/L) levels of fluoride, acetate, formate, chloride, phosphate, and sulfate in high purity water using ion chromatography in combination with sample preconcentration.
1.1These test methods cover the determination of trace (μg/L) levels of fluoride, acetate, formate, chloride, phosphate, and sulfate in high purity water using ion chromatography in combination with sample preconcentration. Other anions, such as bromide, nitrite, nitrate, sulfite, and iodide can be determined by this method. However, since they are rarely present in significant concentrations in high purity water, they are not included in this test method. Two test methods are presented and their ranges of application, as determined by a collaborative study, are as follows:
| Range Tested | Limit of DetectionA | Sections | |
| Test Method A: | 7–16 | ||
| Chloride | 0–24 | 0.8 | |
| Phosphate | 0–39 | B | |
| Sulfate | 0–55 | 1.8 | |
| Test Method B: | 17–24 | ||
| Fluoride | 0–14 | 0.7 | |
| Acetate | 0–414 | 6.8 | |
| Formate | 0–346 | 5.6 |
1.2It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.
1.3The common practical range of Test Method A is as follows: chloride, 1 to 100 μg/L, phosphate, 3 to 100 μg/L, and sulfate, 2 to 100 μg/L.
1.4The common practical range of Test Method B is as follows: fluoride, 1 to 100 μg/L, acetate, 10 to 200 μg/L, and formate, 5 to 200 μg/L.
1.5The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
| Committee |
D 19
|
| DocumentType |
Test Method
|
| Pages |
13
|
| PublisherName |
American Society for Testing and Materials
|
| Status |
Current
|
| Supersedes |
| ASTM D 5996 : 2016 | Standard Test Method for Measuring Anionic Contaminants in High-Purity Water by On-Line Ion Chromatography |
| ASTM D 8149 : 2017 | Standard Practice for Optimization, Calibration, and Validation of Ion Chromatographic Determination of Heteroatoms and Anions in Petroleum Products and Lubricants |
| ASTM D 5196 : 2006 : R2018 | Standard Guide for Bio-Applications Grade Water |
| ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
| ASTM D 5810 : 1996 : R2021 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 3370 : 1995 : REV A : R2003 : EDT 1 | Standard Practices for Sampling Water from Closed Conduits |
| ASTM D 1129 : 2003 | Standard Terminology Relating to Water |
| ASTM D 1129 : 2013 | Standard Terminology Relating to Water |
| ASTM D 1129 : 2013 : R2020 | Standard Terminology Relating to Water |
| ASTM D 5847 : 1999 : REV A : EDT 1 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 5810 : 1996 : R2011 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 1129 : 2013 : R2020 : EDT 2 | Standard Terminology Relating to Water |
| ASTM D 1193 : 1977 : R1983 : EDT 1 | Standard Specification for Reagent Water |
| ASTM D 5847 : 2002 : R2007 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 5810 : 1996 : R2001 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 1129 : 2006 | Standard Terminology Relating to Water |
| ASTM D 4453 : 2002 | Standard Practice for Handling of Ultra-Pure Water Samples |
| ASTM D 1066 : 2018 | Standard Practice for Sampling Steam |
| ASTM D 3370 : 2010 | Standard Practices for Sampling Water from Closed Conduits |
| ASTM D 1066 : 2006 | Standard Practice for Sampling Steam |
| ASTM D 5847 : 2002 : R2012 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 1066 : 2018 : EDT 1 | Standard Practice for Sampling Steam |
| ASTM D 1129 : 2013 : R2020 : EDT 1 | Standard Terminology Relating to Water |
| ASTM D 3370 : 2008 | Standard Practices for Sampling Water from Closed Conduits |
| ASTM D 1129 : 1999 : REV A | Standard Terminology Relating to Water |
| ASTM D 3856 : 2011 | Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water |
| ASTM D 1129 : 2006 : REV A | Standard Terminology Relating to Water |
| ASTM D 1193 : 2006 : R2011 | Standard Specification for Reagent Water |
| ASTM D 5847 : 2002 : R2020 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 1129 : 2003 : REV A | Standard Terminology Relating to Water |
| ASTM D 1129 : 2002 | Standard Terminology Relating to Water |
| ASTM D 1066 : 1997 : R2001 | Standard Practice for Sampling Steam |
| ASTM D 5810 : 1996 : R2006 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 4453 : 1991 : R1997 | Standard Practice for Handling of Ultra-Pure Water Samples |
| ASTM D 1193 : 1991 | Standard Specification for Reagent Water |
| ASTM D 3856 : 1995 : R2006 | Standard Guide for Good Laboratory Practices in Laboratories Engaged in Sampling and Analysis of Water |
| ASTM D 1066 : 2011 | Standard Practice for Sampling Steam |
| ASTM D 1129 : 2004 | Standard Terminology Relating to Water |
| ASTM D 5847 : 2022 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 3856 : 2011 : R2015 | Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water (Withdrawn 2024) |
| ASTM D 1192 : 1998 | Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003) |
| ASTM D 3856 : 1995 : R2000 | Standard Guide for Good Laboratory Practices in Laboratories Engaged in Sampling and Analysis of Water |
| ASTM D 3370 : 2018 | Standard Practices for Sampling Water from Flowing Process Streams |
| ASTM D 1129 : 2002 : REV A | Standard Terminology Relating to Water |
| ASTM D 5847 : 2002 | Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis |
| ASTM D 3370 : 1976 | Standard Practices for Sampling Water |
| ASTM D 4453 : 2017 | Standard Practice for Handling of High Purity Water Samples |
| ASTM D 1193 : 1970 | Standard Specification For Reagent Water |
| ASTM D 1193 : 2006 | Standard Specification for Reagent Water |
| ASTM D 3370 : 1995 : REV A : R1999 : EDT 1 | Standard Practices for Sampling Water from Closed Conduits |
| ASTM D 4453 : 2002 : R2006 | Standard Practice for Handling of Ultra-Pure Water Samples |
| ASTM D 1193 : 1999 | Standard Specification for Reagent Water |
| ASTM D 1129 : 2010 | Standard Terminology Relating to Water |
| ASTM D 4210 : 1989 : R1996 : EDT 1 | Standard Practice for Intralaboratory Quality Control Procedures and a Discussion on Reporting Low-Level Data (Withdrawn 2002) |
| ASTM D 5810 : 1996 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 4453 : 2011 | Standard Practice for Handling of High Purity Water Samples |
| ASTM D 3370 : 2007 | Standard Practices for Sampling Water from Closed Conduits |
| ASTM D 1129 : 2006 : REV A : EDT 1 | Standard Terminology Relating to Water |
| ASTM D 1129 : 2001 | Standard Terminology Relating to Water |
| ASTM D 1129 : 2004 : EDT 1 | Standard Terminology Relating to Water |
| ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
| ASTM D 5810 : 1996 : R2015 | Standard Guide for Spiking into Aqueous Samples |
| ASTM D 4453 : 2016 | Standard Practice for Handling of High Purity Water Samples |
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