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ASTM D 2036 : 2009 : R2015

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Methods for Cyanides in Water
Available format(s)

Hardcopy , PDF

Superseded date

06-18-2022

Language(s)

English

Published date

08-11-2015

These test methods cover the determination of cyanides in water.

1.1These test methods cover the determination of cyanides in water. The following test methods are included:

Sections

Test Method A
 Total Cyanides after Distillation

12 – 18

Test Method B
 Cyanides Amenable to Chlorination2
 by Difference

19 – 25

Test Method C
 Weak Acid Dissociable Cyanides

26 – 32

Test Method D
 Cyanides Amenable to Chlorination without
 Distillation (Short-Cut Method)

33 – 39

1.2Cyanogen halides may be determined separately.

Note 1:Cyanogen chloride is the most common of the cyanogen halide complexes as it is a reaction product and is usually present when chlorinating cyanide-containing industrial waste water. For the presence or absence of CNCl, the spot test method given in Annex A1 can be used.

1.3These test methods do not distinguish between cyanide ions and metallocyanide compounds and complexes. Furthermore, they do not detect the cyanates. Cyanates can be determined using ion chromatography without digestion.

Note 2:The cyanate complexes are decomposed when the sample is acidified in the distillation procedure.

1.4The cyanide in cyanocomplexes of gold, platinum, cobalt and some other transition metals is not completely recovered by these test methods. Refer to Test Method D6994 for the determination of cyanometal complexes.

1.5Cyanide from only a few organic cyanides are recovered, and those only to a minor extent.

1.6Part or all of these test methods have been used successfully with reagent water and various waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.

1.7The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.8This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in 5.1, 8.8, 8.18, Section 9, 11.3, and 16.1.9.

Committee
D 19
DocumentType
Test Method
Pages
20
ProductNote
Reconfirmed 2015
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 7365 : 2009 : REV A : R2022 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM D 7572 : 2015 : R2022 Standard Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil
ASTM D 3694 : 1996 : R2017 Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
ASTM D 7572 : 2015 Standard Guide for Recovery of Aqueous Cyanides by Extraction from Mine Rock and Soil
ASTM D 4193 : 2008 : R2013 : EDT 1 Standard Test Method for Thiocyanate in Water
ASTM D 7365 : 2009 : REV A : R2015 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM D 7284 : 2013 : R2017 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM E 800 : 2014 Standard Guide for Measurement of Gases Present or Generated During Fires
ASTM D 6888 : 2016 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 4165 : 2006 : R2012 Standard Test Method for Cyanogen Chloride in Water
ASTM D 7511 : 2012 : R2017 : EDT 1 Standard Test Method for Total Cyanide by Segmented Flow Injection Analysis, In-Line Ultraviolet Digestion and Amperometric Detection
ASTM D 7237 : 2018 Standard Test Method for Free Cyanide and Aquatic Free Cyanide with Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 7295 : 2018 Standard Practice for Sampling Combustion Effluents and Other Stationary Sources for the Subsequent Determination of Hydrogen Cyanide
ASTM D 7728 : 2018 Standard Guide for Selection of ASTM Analytical Methods for Implementation of International Cyanide Management Code Guidance
ASTM D 4193 : 2008 : R2020 : EDT 1 Standard Test Method for Thiocyanate in Water
ASTM D 4165 : 2006 : R2020 : EDT 1 Standard Test Method for Cyanogen Chloride in Water
ASTM E 800 : 2020 Standard Guide for Measurement of Gases Present or Generated During Fires
ASTM D 7284 : 2020 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection

ASTM D 6994 : 2010 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
ASTM D 7365 : 2007 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM D 1129 : 2013 : REDLINE Standard Terminology Relating to Water
ASTM D 1129 : 2003 Standard Terminology Relating to Water
ASTM D 2777 : 2013 : REDLINE Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 7365 : 2009 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM D 5788 : 1995 : R2001 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 5788 : 1995 : R2017 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 1129 : 2013 Standard Terminology Relating to Water
ASTM D 1129 : 2013 : R2020 Standard Terminology Relating to Water
ASTM D 5847 : 1999 : REV A : EDT 1 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 6888 : 2003 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 6696 : 2016 : REDLINE Standard Guide for Understanding Cyanide Species
ASTM D 7284 : 2013 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 6994 : 2004 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
ASTM D 6696 : 2016 Standard Guide for Understanding Cyanide Species
ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
ASTM D 5847 : 2002 : R2007 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 5788 : 1995 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 6888 : 2016 Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 6696 : 2010 Standard Guide for Understanding Cyanide Species
ASTM D 1129 : 2006 Standard Terminology Relating to Water
ASTM D 6696 : 2014 Standard Guide for Understanding Cyanide Species
ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 6994 : 2015 : REDLINE Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM E 275 : 2008 Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
ASTM E 275 : 2008 : R2013 Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
ASTM D 7365 : 2009 : REV A Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM E 275 : 2008 : R2022 Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
ASTM D 6696 : 2005 : EDT 1 Standard Guide for Understanding Cyanide Species
ASTM D 5847 : 2002 : R2012 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
ASTM D 1129 : 1999 : REV A Standard Terminology Relating to Water
ASTM D 6888 : 2009 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 1129 : 2006 : REV A Standard Terminology Relating to Water
ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
ASTM D 6888 : 2004 Standard Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 5847 : 2002 : R2020 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 1129 : 2003 : REV A Standard Terminology Relating to Water
ASTM D 1129 : 2002 Standard Terminology Relating to Water
ASTM D 6696 : 2005 Standard Guide for Understanding Cyanide Species
ASTM D 7284 : 2008 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM D 7284 : 2008 : EDT 1 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM D 5788 : 1995 : R2005 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 5788 : 1995 : R2011 Standard Guide for Spiking Organics into Aqueous Samples
ASTM D 1193 : 1991 Standard Specification for Reagent Water
ASTM D 1129 : 2004 Standard Terminology Relating to Water
ASTM D 7284 : 2013 : R2017 Standard Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
ASTM D 6696 : 2001 Standard Guide for Understanding Cyanide Species
ASTM D 1129 : 2002 : REV A Standard Terminology Relating to Water
ASTM D 5847 : 2002 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
ASTM D 7365 : 2009 : REV A : R2015 Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
ASTM D 1193 : 1970 Standard Specification For Reagent Water
ASTM D 1193 : 2006 Standard Specification for Reagent Water
ASTM D 1193 : 1999 Standard Specification for Reagent Water
ASTM D 1129 : 2010 Standard Terminology Relating to Water
ASTM D 1129 : 2006 : REV A : EDT 1 Standard Terminology Relating to Water
ASTM D 1129 : 2001 Standard Terminology Relating to Water
ASTM D 6994 : 2015 Standard Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
ASTM D 1129 : 2004 : EDT 1 Standard Terminology Relating to Water
ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
ASTM D 6888 : 2016 : REDLINE Standard Test Method for Available Cyanides with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

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