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ASTM D 5191 : 2012

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Vapor Pressure of Petroleum Products (Mini Method)
Available format(s)

Hardcopy , PDF

Superseded date

11-11-2014

Language(s)

English

Published date

09-01-2012

1.1This test method covers the use of automated vapor pressure instruments to determine the total vapor pressure exerted in vacuum by air-containing, volatile, liquid petroleum products, including automotive spark-ignition fuels with or without oxygenates (see Note 1). This test method is suitable for testing samples with boiling points above 0°C (32°F) that exert a vapor pressure between 7 and 130 kPa (1.0 and 18.6 psi) at 37.8°C (100°F) at a vapor-to-liquid ratio of 4:1. Measurements are made on liquid sample sizes in the range from 1 to 10 mL. No account is made for dissolved water in the sample.

Note 1An interlaboratory study was conducted in 2008 involving 11 different laboratories submitting 15 data sets and 15 different samples of ethanol-fuel blends containing 25 volume %, 50 volume %, and 75 volume % ethanol. The results indicated that the repeatability limits of these samples are with in the published repeatability of this test method. on this basis, it can be concluded that D5191 is applicable to ethanol-fuel blends such as Ed75 and Ed85 (Specification D5798) and other ethanol-fuel blends with greater than 10 v% ethanol. See ASTM RR: D02–1694 filed with ASTM for supporting data.2
Note 2Samples can also be tested at other vapor-to-liquid ratios, temperatures, and pressures, but the precision and bias statements need not apply.
Note 3The interlaboratory studies conducted in 1988, 1991, and 2003 to determine the precision statements in Test Method D5191 did not include any crude oil in the sample sets. Test Method D6377, as well as IP 481, have been shown to be suitable for vapor pressure measurements of crude oils.

1.1.1Some gasoline-oxygenate blends may show a haze when cooled to 0 to 1°C. If a haze is observed in 8.5, it shall be indicated in the reporting of results. The precision and bias statements for hazy samples have not been determined (see Note 15).

1.2This test method is suitable for calculation of the dry vapor pressure equivalent (DVPE) of gasoline and gasoline-oxygenate blends by means of a correlation equation (see Eq 1 in 14.2). The calculated DVPE very closely approximates the dry vapor pressure that would be obtained on the same material when tested by Test Method D4953.

1.3The values stated in SI units are regarded as standard. The inch-pound units given in parentheses are provided for information only.

1.4WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website – http://www.epa.gov/mercury/faq.htm - for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.

1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safety warning statements, see 7.2 through 7.8.

Committee
D 02
DocumentType
Test Method
Pages
9
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 4953 : 2015 Standard Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method)
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ASTM D 6201 : 2018 : REV A Standard Test Method for Dynamometer Evaluation of Unleaded Spark-Ignition Engine Fuel for Intake Valve Deposit Formation
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ASTM D 7794 : 2018 : REV A Standard Practice for Blending Mid-Level Ethanol Fuel Blends for Flexible-Fuel Vehicles with Automotive Spark-Ignition Engines
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ASTM D 4057 : 2012 : R2018 Standard Practice for Manual Sampling of Petroleum and Petroleum Products
ASTM D 4052 : 2018 : REV A Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
ASTM D 7719 : 2018 Standard Specification for High Aromatic Content Unleaded Hydrocarbon Aviation Gasoline
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ASTM D 6227 : 2018 Standard Specification for Unleaded Aviation Gasoline Containing a Non-hydrocarbon Component
ASTM D 7235 : 2016 Standard Guide for Establishing a Linear Correlation Relationship Between Analyzer and Primary Test Method Results Using Relevant ASTM Standard Practices
ASTM D 7566 : 2019 Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons
ASTM D 6792 : 2017 Standard Practice for Quality Management Systems in Petroleum Products, Liquid Fuels, and Lubricants Testing Laboratories
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ASTM D 7547 : 2018 : REV A Standard Specification for Hydrocarbon Unleaded Aviation Gasoline
ASTM D 6897 : 2016 Standard Test Method for Vapor Pressure of Liquefied Petroleum Gases (LPG) (Expansion Method)
ASTM D 7345 : 2017 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Micro Distillation Method)
ASTM D 7096 : 2019 Standard Test Method for Determination of the Boiling Range Distribution of Gasoline by Wide-Bore Capillary Gas Chromatography
ASTM D 5482 : 2007 : R2013 Standard Test Method for Vapor Pressure of Petroleum Products (Mini Method—Atmospheric)
ASTM D 7975 : 2014 Standard Test Method for Determination of Vapor Pressure of Crude Oil: <brk/>VPCR<inf >x</inf>-F(Tm°C)(Manual Expansion Field Method)
ASTM D 4814 : 2019 Standard Specification for Automotive Spark-Ignition Engine Fuel
ASTM D 6378 : 2018 : REV A Standard Test Method for Determination of Vapor Pressure (VP<inf>X</inf>) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)

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