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ASTM D 6196 : 2015 : EDT 1

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Practice for Choosing Sorbents, Sampling Parameters and Thermal Desorption Analytical Conditions for Monitoring Volatile Organic Chemicals in Air
Available format(s)

Hardcopy , PDF

Superseded date

03-17-2023

Language(s)

English

Published date

07-06-2018

1.1This practice is intended to assist in the selection of sorbents and procedures for the sampling and analysis of ambient (1),2 indoor (2), and workplace (3, 4) atmospheres for a variety of common volatile organic compounds (VOCs). It may also be used for measuring emissions from materials in small or full scale environmental chambers or for human exposure assessment.

1.2This practice is based on the sorption of VOCs from air onto selected sorbents or combinations of sorbents. Sampled air is either drawn through a tube containing one or a series of sorbents (pumped sampling) or allowed to diffuse, under controlled conditions, onto the sorbent surface at the sampling end of the tube (diffusive or passive sampling). The sorbed VOCs are subsequently recovered by thermal desorption and analyzed by capillary gas chromatography.

1.3This practice applies to three basic types of samplers that are compatible with thermal desorption: (1) pumped sorbent tubes containing one or more sorbents; (2) axial passive (diffusive) samplers (typically of the same physical dimensions as standard pumped sorbent tubes and containing only one sorbent); and (3) radial passive (diffusive) samplers.

1.4This practice recommends a number of sorbents that can be packed in sorbent tubes for use in the sampling of vapor-phase organic chemicals; including volatile and semi-volatile organic compounds which, generally speaking, boil in the range 0 to 400°C (v.p. 15 to 0.01 kPa at 25°C).

1.5This practice can be used for the measurement of airborne vapors of these organic compounds over a wide concentration range.

1.5.1With pumped sampling, this practice can be used for the speciated measurement of airborne vapors of VOCs in a concentration range of approximately 0.1 μg/m3 to 1 g/m3, for individual organic compounds in 1–10 L air samples. Quantitative measurements are possible when using validated procedures with appropriate quality control measures.

1.5.2With axial diffusive sampling, this practice is valid for the speciated measurement of airborne vapors of volatile organic compounds in a concentration range of approximately 100 µg/m3 to 100 mg/m3 for individual organic compounds for an exposure time of 8 h or 1 µg/m3 to 1 mg/m3 for individual organic compounds for an exposure time of four weeks.

1.5.3With radial diffusive sampling, this practice is valid for the measurement of airborne vapors of volatile organic compounds in a concentration range of approximately 5 µg/m3 to 5 mg/m3 for individual organic compounds for exposure times of one to six hours.

1.5.4The upper limit of the useful range is almost always set by the linear dynamic range of the gas chromatograph column and detector, or by the sample splitting capability of the analytical instrumentation used.

1.5.5The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte or interfering artifacts (or both) on the sorbent tubes.

1.6This procedure can be used for personal and fixed location sampling. It cannot be used to measure instantaneous or short-term fluctuations in concentration. Alternative ‘grab sampling’ procedures using canister air samplers (for example, Test Method D5466) may be suitable for monitoring instantaneous or short term fluctuations in air concentration. Alternatives for on-site measurement include, but are not limited to, gas chromatography, real-time mass spectrometry detectors and infrared spectrometry.

1.7The sampling method gives a time-weighted average result.

1.8The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.9This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.10This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 22
DocumentType
Standard Practice
Pages
31
ProductNote
ε1 NOTE—Editorial corrections were made throughout in July 2018.
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 6177 : 2019 Standard Practice for Determining Emission Profiles of Volatile Organic Chemicals Emitted from Bedding Sets
ASTM D 7663 : 2012 : R2018 : EDT 1 Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations
ASTM D 1356 : 2020 : REV A Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM E 800 : 2020 Standard Guide for Measurement of Gases Present or Generated During Fires
ASTM D 6330 : 2020 Standard Practice for Determination of Volatile Organic Compounds (Excluding Formaldehyde) Emissions from Wood-Based Panels Using Small Environmental Chambers Under Defined Test Conditions
ASTM D 7297 : 2021 Standard Practice for Evaluating Residential Indoor Air Quality Concerns
ASTM D 8345 : 2021 Standard Test Method for Determination of an Emission Parameter for Phthalate Esters and Other Non-Phthalate Plasticizers from Planar Polyvinyl Chloride Indoor Materials for Use in Mass Transfer Modeling Calculations
ASTM D 7911 : 2019 Standard Guide for Using Reference Material to Characterize Measurement Bias Associated with Volatile Organic Compound Emission Chamber Test
ASTM D 6803 : 2019 Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers
ASTM D 8142 : 2017 : EDT 1 Standard Test Method for Determining Chemical Emissions from Spray Polyurethane Foam (SPF) Insulation using Micro-Scale Environmental Test Chambers
ASTM D 3687 : 2019 Standard Test Method for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method
ASTM D 3687 : 2007 : R2012 Standard Practice for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method
ASTM D 6330 : 1998 : R2014 Standard Practice for Determination of Volatile Organic Compounds (Excluding Formaldehyde) Emissions from Wood-Based Panels Using Small Environmental Chambers Under Defined Test Conditions
ASTM D 6670 : 2018 Standard Practice for Full-Scale Chamber Determination of Volatile Organic Emissions from Indoor Materials/Products
ASTM D 7648/D7648M : 2018 Standard Practice for Active Soil Gas Sampling for Direct Push or Manual-Driven Hand-Sampling Equipment
ASTM D 6399 : 2018 Standard Guide for Selecting Instruments and Methods for Measuring Air Quality in Aircraft Cabins
ASTM D 1356 : 2017 Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM D 5116 : 2017 Standard Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions from Indoor Materials/Products
ASTM D 6177 : 2014 Standard Practice for Determining Emission Profiles of Volatile Organic Chemicals Emitted from Bedding Sets
ASTM D 6306 : 2017 Standard Guide for Placement and Use of Diffusive Samplers for Gaseous Pollutants in Indoor Air
ASTM D 6803 : 2013 Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Paint Using Small Environmental Chambers
ASTM D 7143 : 2017 Standard Practice for Emission Cells for the Determination of Volatile Organic Emissions from Indoor Materials/Products
ASTM D 7297 : 2014 Standard Practice for Evaluating Residential Indoor Air Quality Concerns
ASTM D 7339 : 2018 Standard Test Method for Determination of Volatile Organic Compounds Emitted from Carpet using a Specific Sorbent Tube and Thermal Desorption / Gas Chromatography
ASTM D 7706 : 2017 Standard Practice for Rapid Screening of VOC Emissions from Products Using Micro-Scale Chambers
ASTM D 7758 : 2017 Standard Practice for Passive Soil Gas Sampling in the Vadose Zone for Source Identification, Spatial Variability Assessment, Monitoring, and Vapor Intrusion Evaluations
ASTM D 7911 : 2014 Standard Guide for Using Reference Material to Characterize Measurement Bias Associated with Volatile Organic Compound Emission Chamber Test
ASTM D 8142 : 2017 Standard Test Method for Determining Chemical Emissions from Spray Polyurethane Foam (SPF) Insulation using Micro-Scale Environmental Test Chambers

ASTM D 3670 : 1991 : R1996 : EDT 1 Standard Guide for Determination of Precision and Bias of Methods of Committee D22
ASTM D 5466 : 1995 Standard Test Method for Determination of Volatile Organic Chemicals in Atmospheres (Canister Sampling Methodology)
ASTM D 1356 : 2015 Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM D 5466 : 2015 Standard Test Method for Determination of Volatile Organic Compounds in Atmospheres (Canister Sampling Methodology)
ASTM D 3670 : 1991 : R2022 Standard Guide for Determination of Precision and Bias of Methods of Committee D22
ASTM D 3670 : 1991 : R2014 Standard Guide for Determination of Precision and Bias of Methods of Committee D22
ASTM D 3686 : 1995 Standard Practice for Sampling Atmospheres to Collect Organic Compound Vapors (Activated Charcoal Tube Adsorption Method)
ASTM E 355 : 1996 : R2021 : EDT 1 Standard Practice for Gas Chromatography Terms and Relationships
ASTM D 3670 : 1991 : R2001 Standard Guide for Determination of Precision and Bias of Methods of Committee D22
ASTM D 1356 : 2015 : REV A Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM D 1356 : 2000 : REV A Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM D 1356 : 2014 : REV B Standard Terminology Relating to Sampling and Analysis of Atmospheres
ASTM D 5466 : 2021 Standard Test Method for Determination of Volatile Organic Compounds in Atmospheres (Canister Sampling, Mass Spectrometry Analysis Methodology)
ASTM E 355 : 1996 : R2014 Standard Practice for Gas Chromatography Terms and Relationships

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