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ASTM D 6228 : 2019

Current
Current

The latest, up-to-date edition.

Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Photometric Detection
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

12-05-2023

This test method covers the determination of individual volatile sulfur-containing compounds in gaseous fuels by gas chromatography (GC) with a flame photometric detector (FPD) or a pulsed flame photometric detector (PFPD). The detection range for sulfur compounds is from 20 to 20 000 picograms (pg) of sulfur.

1.1This test method covers the determination of individual volatile sulfur-containing compounds in gaseous fuels by gas chromatography (GC) with a flame photometric detector (FPD) or a pulsed flame photometric detector (PFPD). The detection range for sulfur compounds is from 20 to 20 000 picograms (pg) of sulfur. This is equivalent to 0.02 to 20 mg/m3 or 0.014 to 14 ppmv of sulfur based upon the analysis of a 1 mL sample.

1.2This test method describes a GC method using capillary column chromatography with either an FPD or PFPD.

1.3This test method does not intend to identify all individual sulfur species. Total sulfur content of samples can be estimated from the total of the individual compounds determined. Unknown compounds are calculated as monosulfur-containing compounds.

1.4The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.5This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Committee
D 03
DocumentType
Test Method
Pages
9
ProductNote
THIS STANDARD ALSO REFERES TO : EPA–15,EPA–16
PublisherName
American Society for Testing and Materials
Status
Current
Supersedes

ASTM D 6968 : 2003 : R2015 Standard Test Method for Simultaneous Measurement of Sulfur Compounds and Minor Hydrocarbons in Natural Gas and Gaseous Fuels by Gas Chromatography and Atomic Emission Detection (Withdrawn 2024)
ASTM D 7551 : 2010 : R2015 Standard Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases and Natural Gas by Ultraviolet Fluorescence
ASTM D 7800/D7800M : 2014 Standard Test Method for Determination of Elemental Sulfur in Natural Gas (Withdrawn 2023)
ASTM D 7165 : 2010 : R2015 Standard Practice for Gas Chromatograph Based On-line/At-line Analysis for Sulfur Content of Gaseous Fuels
ASTM D 7165 : 2022 Standard Practice for Gas Chromatograph Based On-line/At-line Analysis for Sulfur Content of Gaseous Fuels
ASTM D 7493 : 2022 Standard Test Method for Online Measurement of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatograph and Electrochemical Detection
ASTM D 8487 : 2023 Standard Specification for Natural Gas, Hydrogen Blends for Use as a Motor Vehicle Fuel
ASTM D 7800/D7800M : 2023 Standard Test Method for Determination of Elemental Sulfur in Natural Gas
ASTM D 8080 : 2021 Standard Specification for Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG) Used as a Motor Vehicle Fuel
ASTM D 8488 : 2022 Standard Test Method for Determination of Hydrogen Sulfide (H<inf>2</inf>S) in Natural Gas by Tunable Diode Laser Spectroscopy (TDLAS)

ASTM D 1265 : 1997 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 3609 : 2000 : R2014 Standard Practice for Calibration Techniques Using Permeation Tubes
ASTM D 4468 : 1985 : R2015 Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<brk/> Rateometric Colorimetry
ASTM D 4468 : 1985 : R2000 Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry
ASTM D 5287 : 1997 Standard Practice for Automatic Sampling of Gaseous Fuels
ASTM D 1945 : 1996 : EDT 1 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 1265 : 2023 : REV A Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 1945 : 1996 : R2001 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 4626 : 1995 : R2005 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D 3609 : 2000 : R2005 Standard Practice for Calibration Techniques Using Permeation Tubes
ASTM D 5504 : 2008 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 5287 : 2008 Standard Practice for Automatic Sampling of Gaseous Fuels
ASTM D 3609 : 2000 : R2010 Standard Practice for Calibration Techniques Using Permeation Tubes
ASTM D 3609 : 2022 Standard Practice for Calibration Techniques Using Permeation Tubes
ASTM D 3609 : 2000 Standard Practice for Calibration Techniques Using Permeation Tubes
ASTM D 5287 : 2008 : R2015 Standard Practice for Automatic Sampling of Gaseous Fuels (Withdrawn 2024)
ASTM D 4626 : 1995 : R2019 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D 1265 : 2004 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 1945 : 2003 : R2010 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 5504 : 1998 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 1945 : 2014 : R2019 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 4468 : 1985 : R2011 Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<br> Rateometric Colorimetry
ASTM D 1265 : 2011 : R2017 : EDT 1 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 1945 : 2003 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 4468 : 1985 : R2006 Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry
ASTM D 4626 : 2023 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM E 840 : 1995 : R2013 Standard Practice for Using Flame Photometric Detectors in Gas Chromatography
ASTM D 4626 : 1995 : R2015 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D 5504 : 2001 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 1265 : 2005 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 5504 : 2001 : R2006 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 4626 : 1995 : R2000 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D 5504 : 2012 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 1265 : 2004 : REV A Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
ASTM D 1265 : 2011 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 5504 : 2020 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
ASTM D 1265 : 2023 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM D 4626 : 1995 : R2010 Standard Practice for Calculation of Gas Chromatographic Response Factors
ASTM D 4468 : 2023 Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and<brk/> Rateometric Colorimetry
ASTM D 1945 : 2014 Standard Test Method for Analysis of Natural Gas by Gas Chromatography
ASTM D 1265 : 2022 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
ASTM E 840 : 1995 : R2021 : EDT 1 Standard Practice for Using Flame Photometric Detectors in Gas Chromatography
ASTM D 1945 : 1991 Standard Test Method for Analysis of Natural Gas by Gas Chromatography

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