• There are no items in your cart

ASTM D 6968 : 2003 : R2009

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Standard Test Method for Simultaneous Measurement of Sulfur Compounds and Minor Hydrocarbons in Natural Gas and Gaseous Fuels by Gas Chromatography and Atomic Emission Detection
Available format(s)

Hardcopy , PDF

Superseded date

01-08-2024

Language(s)

English

Published date

06-01-2009

CONTAINED IN VOL. 05.06, 2015 Defines the determination of volatile sulfur-containing compounds and minor hydrocarbons in gaseous fuels including components with higher molar mass than that of propane in a high methane gas, by gas chromatography (GC) and atomic emission detection (AED).

1.1 This test method is for the determination of volatile sulfur-containing compounds and minor hydrocarbons in gaseous fuels including components with higher molar mass than that of propane in a high methane gas, by gas chromatography (GC) and atomic emission detection (AED). Hydrocarbons include individual aliphatic components from C4 to C6, aromatic components and groups of hydrocarbons classified according to carbon numbers up to C12 at least, such as C6-C7, C7-C8, C8-C9 and C9-C10, etc. The detection range for sulfur and carbon containing compounds is approximately 20 to 100 000 picograms (pg). This is roughly equivalent to 0.04 to 200 mg/m3 sulfur or carbon based upon the analysis of a 0.25 mL sample.

1.2 This test method describes a GC-AED method employing a specific capillary GC column as an illustration for natural gas and other gaseous fuel containing low percentages of ethane and propane. Alternative GC columns and instrument parameters may be used in this analysis optimized for different types of gaseous fuel, provided that appropriate separation of the compounds of interest can be achieved.

1.3 This test method does not intend to identify all individual sulfur species. Unknown sulfur compounds are measured as mono-sulfur containing compounds. Total sulfur content of a sample can be found by summing up sulfur content present in all sulfur species.

1.4 This method is not a Detailed Hydrocarbon Analysis (DHA) method and does not intend to identify all individual hydrocarbon species. Aliphatic hydrocarbon components lighter than n-hexane, benzene, toluene, ethyl benzene, m,p-xylenes and o-xylene (BTEX) are generally separated and identified individually. Higher molar mass hydrocarbons are determined as groups based on carbon number, excluding BTEX. The total carbon content of propane and higher molar mass components in a sample can be found by summing up carbon content present in all species containing carbon.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Committee
D 03
DocumentType
Test Method
Pages
7
ProductNote
Reconfirmed 2009
PublisherName
American Society for Testing and Materials
Status
Superseded
SupersededBy
Supersedes

ASTM D 5504 : 2012 : REDLINE Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence
GPA 2199 : 1999 DETERMINATION OF SPECIFIC SULFUR COMPOUNDS BY CAPILLARY GAS CHROMOTOGRAPHY AND SULFUR CHEMILUMINESCENCE DETECTION
ISO 19739:2004 Natural gas Determination of sulfur compounds using gas chromatography
ASTM D 1945 : 2014 : REDLINE Standard Test Method for Analysis of Natural Gas by Gas Chromatography

View more information
US$75.00
Excluding Tax where applicable

Access your standards online with a subscription

Features

  • Simple online access to standards, technical information and regulations.

  • Critical updates of standards and customisable alerts and notifications.

  • Multi-user online standards collection: secure, flexible and cost effective.