• ASTM D 8018 : 2015

    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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    Standard Test Method for Determination of (Tri-n-butyl)-n-tetradecylphosphonium chloride (TTPC) in Soil by Multiple Reaction Monitoring Liquid Chromatography/Mass Spectrometry (LC/MS/MS)

    Available format(s):  Hardcopy, PDF

    Superseded date:  05-12-2020

    Language(s):  English

    Published date:  11-01-2015

    Publisher:  American Society for Testing and Materials

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    Abstract - (Show below) - (Hide below)

    CONTAINED IN VOL. 11.04, 2017 Defines the determination of (Tri-nbutyl)-n-tetradecylphosphonium chloride (TTPC) in a soil matrix by extraction with acetone, filtration, dilution with water, and analysis by liquid chromatography/tandem mass spectrometry.

    Scope - (Show below) - (Hide below)

    1.1This procedure covers the determination of (Tri-n-butyl)-n-tetradecylphosphonium chloride (TTPC) in a soil matrix by extraction with acetone, filtration, dilution with water, and analysis by liquid chromatography/tandem mass spectrometry. TTPC is a biocide that strongly adsorbs to soils.2 The sample extracts are prepared in a solution of 75 % acetone and 25 % water because TTPC has an affinity for surfaces and particles. The reporting range for this method is from 250 to 10 000 ng/kg. This analyte is qualitatively and quantitatively determine by this method. This method adheres to multiple reaction monitoring (MRM) mass spectrometry.

    1.2The Method Detection Limit (Note 1) (MDL) and Reporting Range (Note 2) for the target analyte are listed in Table 1.

    (A)Acronyms are defined in 3.3.

    Note 1:The MDL is determined following the Code of Federal Regulations, 40 CFR Part 136, Appendix B, as a guide utilizing solvent extraction of soil. Two-gram sample of Ottawa Sand was utilized. A detailed process determining the MDL is explained in the reference and is beyond the scope of this standard to be explained here.

    Note 2:Reporting range concentration is calculated from Table 2 concentrations assuming a 50 μL injection of the Level 1 calibration standard for TTPC, and the highest level calibration standard with a 20 mL final extract volume of a 2 g soil sample. Volume variations will change the reporting limit and ranges.

    1.2.1The reporting limit in this test method is the minimum value below which data are documented as non-detects. Analyte detections between the method detection limit and the reporting limit are estimated concentrations and are not reported following this test method. The reporting limit is calculated from the concentration of the Level 1 calibration standard as shown in Table 2 for TTPC after taking into account a 2 g sample weight and a final extract volume of 20 mL in 75 % acetone/25 % water. The final extract volume is 20 mL because a 15 mL volume of acetone is added to each soil sample and only the liquid layer after extraction is filtered leaving the solid behind followed by the addition of 5 mL of water to the acetone extract.

    1.3Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    General Product Information - (Show below) - (Hide below)

    Committee D 34
    Document Type Test Method
    Publisher American Society for Testing and Materials
    Status Superseded
    Superseded By

    Standards Referencing This Book - (Show below) - (Hide below)

    ASTM D 5681 : 2017 Standard Terminology for Waste and Waste Management
    ASTM D 2777 : 2013 : REDLINE Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 5847 : 1999 : REV A : EDT 1 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 5681 : 2008 Standard Terminology for Waste and Waste Management
    ASTM D 2777 : 2012 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 5681 : 2018 Standard Terminology for Waste and Waste Management
    ASTM D 1193 : 1977 : R1983 : EDT 1 Standard Specification for Reagent Water
    ASTM D 5847 : 2002 : R2007 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 2777 : 2003 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 2777 : 2013 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 2554 : 2013 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 5847 : 2002 : R2012 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 5681 : 1998 : REV A Standard Terminology for Waste and Waste Management
    ASTM D 2777 : 1998 Standard Practice for Determination of Precision and Bias of Applicable Methods of Committee D-19 on Water
    ASTM D 5681 : 2016 Standard Terminology for Waste and Waste Management
    ASTM D 1193 : 2006 : R2011 Standard Specification for Reagent Water
    ASTM D 5681 : 2009 Standard Terminology for Waste and Waste Management
    ASTM E 2554 : 2018 : EDT 1 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 1193 : 1991 Standard Specification for Reagent Water
    ASTM D 5681 : 1998 : REV A : EDT 1 Standard Terminology for Waste and Waste Management
    ASTM D 2777 : 2008 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 2554 : 2007 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method in a Single Laboratory Using a Control Sample Program
    ASTM D 5681 : 1998 : REV A : R2004 Standard Terminology for Waste and Waste Management
    ASTM D 2777 : 2006 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM E 2554 : 2018 Standard Practice for Estimating and Monitoring the Uncertainty of Test Results of a Test Method Using Control Chart Techniques
    ASTM D 5681 : 2016 : REV A Standard Terminology for Waste and Waste Management
    ASTM D 5847 : 2002 Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
    ASTM D 5681 : 1998 : REV A : R2004 : EDT 1 Standard Terminology for Waste and Waste Management
    ASTM E 2554 : 2013-05 PRACTICE FOR ESTIMATING AND MONITORING THE UNCERTAINTY OF TEST RESULTS OF A TEST METHOD USING CONTROL CHART TECHNIQUES
    ASTM D 1193 : 1970 Standard Specification For Reagent Water
    ASTM D 1193 : 2006 Standard Specification for Reagent Water
    CFR 40(PTS136-149) : JUL 2017 PROTECTION OF ENVIRONMENT - ENVIRONMENTAL PROTECTION AGENCY
    ASTM D 1193 : 1999 Standard Specification for Reagent Water
    ASTM D 1193 : 2006 : R2018 Standard Specification for Reagent Water
    ASTM D 2777 : 2008 : EDT 1 Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
    ASTM D 5681 : 2013 Standard Terminology for Waste and Waste Management
    ASTM D 5681 : 2017-09 TERMINOLOGY FOR WASTE AND WASTE MANAGEMENT
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