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CEN/TR 15106:2005

Current

Current

The latest, up-to-date edition.

Fertilizers - Determination of chelating agents EDDHA and EDDHMA by ion pair chromatography - Comparison of non-standardized Lucena method with EN 13368-2:2001

Published date

05-11-2005

Foreword
Introduction
1 Scope
2 Normative references
3 Test procedure for ring test A
4 Test procedure for ring test B
5 Final conclusion
Annex A (informative) Non-standardized method:
                      "Fertilizers - Determination of
                      Fe chelated by the chelating agents
                      EDDHA and EDDHMA in fertilizers by
                      ion pair chromatography"
Annex B (informative) Comments received from the participating
                      laboratories and suggestions of
                      CEN/TC 260/WG 5 for improvement of
                      the non-standardized method
Annex C (informative) Suggestions received from the
                      participating laboratories of
                      CEN/TC 260/WG 5 after ring test B
Bibliography

This Technical Report covers the results from two ring tests (A and B, see Introduction) to compare the repeatability and reproducibility of the standardized method for the determination of EDDHA and EDDHMA by ion chromatography (EN 13368 2:2001) with a non-standardized alternative method using ion-pair chromatography ("Lucena-method", given in Annex A). This Technical Report also provides the results of an univariate multifactorial ANOVA test and F-test for ring test A and F-test for ring test B to verify the significance of the reproducibility and the repeatability data.

Committee
CEN/TC 260
DocumentType
Technical Report
PublisherName
Comite Europeen de Normalisation
Status
Current

Standards Relationship
I.S. CEN/TR 15106:2005 Identical
NEN NPR CEN/TR 15106 : 2005 Identical
UNI CEN/TR 15106 : 2005 Identical
UNE-CEN/TR 15106:2005 IN Identical

BS EN 13368-2:2017 Fertilizers. Determination of chelating agents in fertilizers by chromatography Determination of Fe chelated by [o,o] EDDHA, [o,o] EDDHMA and HBED, or the amount of chelating agents, by ion pair chromatography
BS EN 13368-3:2017 Fertilizers. Determination of chelating agents in fertilizers by chromatography Determination of [S,S]-EDDS by ion pair chromatography
16/30340656 DC : 0 BS EN 13368-2 - FERTILIZERS - DETERMINATION OF CHELATING AGENTS IN FERTILIZERS BY CHROMATOGRAPHY - PART 2: DETERMINATION OF FE CHELATED BY [O,O] EDDHA, [O,O] EDDHMA AND HBED, OR THE AMOUNT OF CHELATING AGENTS, BY ION PAIR CHROMATOGRAPHY
PREN 13368-2 : DRAFT 2016 FERTILIZERS - DETERMINATION OF CHELATING AGENTS IN FERTILIZERS BY CHROMATOGRAPHY - PART 2: DETERMINATION OF FE CHELATED BY [O,O] EDDHA, [O,O] EDDHMA AND HBED, OR THE AMOUNT OF CHELATING AGENTS, BY ION PAIR CHROMATOGRAPHY
05/30136174 DC : DRAFT JULY 2005 EN 13368-2 - FERTILIZERS - DETERMINATION OF CHELATING AGENTS IN FERTILIZERS BY CHROMATOGRAPHY - PART 2: DETERMINATION OF FE CHELATED BY O,O-EDDHA AND O,O-EDDHMA BY ION PAIR CHROMATOGRAPHY
11/30238479 DC : 0 BS EN 13368-2 - FERTILIZERS - DETERMINATION OF CHELATING AGENTS IN FERTILIZERS BY CHROMATOGRAPHY - PART 2: DETERMINATION OF FE CHELATED BY O,O-EDDHA, O,O-EDDHMA AND HBED BY ION PAIR CHROMATOGRAPHY
EN 13368-2:2017 Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determination of Fe chelated by [o,o] EDDHA, [o,o] EDDHMA and HBED, or the amount of chelating agents, by ion pair chromatography
EN 13368-3:2017 Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 3: Determination of [S,S]-EDDS by ion pair chromatography
I.S. EN 13368-2:2017 FERTILIZERS - DETERMINATION OF CHELATING AGENTS IN FERTILIZERS BY CHROMATOGRAPHY - PART 2: DETERMINATION OF FE CHELATED BY [O,O] EDDHA, [O,O] EDDHMA AND HBED, OR THE AMOUNT OF CHELATING AGENTS, BY ION PAIR CHROMATOGRAPHY

ISO 5725-2:1994 Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method

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