Name: CEN/TS 16182:2012
Brand: CEN

Sludge treated biowaste and soil - Determination of nonylphenols (NP) and nonylphenol-mono- and diethoxylates using gas chromatography with mass selective detection (GC-MS)

Published date

02-22-2012

Publisher

Comite Europeen de Normalisation

Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interferences
5 Reagents
6 Apparatus
7 Sample storage and sample pretreatment
8 Procedure
9 Calculation and expression of results
10 Precision
11 Test report
Annex A (informative) - Repeatability and reproducibility
data
Annex B (informative) - Example of chromatographic
conditions and example of a chromatogram
Bibliography

This Technical Specification specifies a method for the determination of nonylphenols (NP), nonylphenol-monoethoxylates (NP1EO) and nonylphenol-diethoxylates (NP2EO) in sludge using GC-MS. For sludge a limit of detection of 0,1 mg/kg and for soil and treated bio-waste 0,02 mg/kg (expressed as dry matter) may be achieved.Lower limits of detection may be achieved by concentrating the extract by solvent evaporation.NOTE4-tert-octylphenol can also be analysed with this method.

Committee	CEN/TC 444
DocumentType	Technical Specification
PublisherName	Comite Europeen de Normalisation
Status	Current

Standards	Relationship
DIN CEN/TS 16182; DIN SPEC 91262:2012-05	Identical
XP CEN/TS 16182 : 2012 XP	Identical
S.R. CEN/TS 16182:2012	Identical
UNI CEN/TS 16182 : 2012	Identical
DIN CEN/TS 16182;DIN SPEC 91262:2012-05	Identical

ISO 18857-1:2005	Water quality — Determination of selected alkylphenols — Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection
PREN 15934 : DRAFT 2009	SOIL, SLUDGE, WASTE, AND TREATED BIOWASTE - DETERMINATION OF DRY MATTER - GRAVIMETRIC METHOD
EN ISO 18857-1:2006	Water quality - Determination of selected alkylphenols - Part 1: Method for non-filtered samples using liquid-liquid extraction and gas chromatography with mass selective detection (ISO 18857-1:2005)
ISO 22892:2006	Soil quality Guidelines for the identification of target compounds by gas chromatography and mass spectrometry
PREN 16179 : DRAFT 2010	SLUDGE, TREATED BIOWASTE AND SOIL - GUIDANCE FOR SAMPLE PRETREATMENT
ISO 18857-2:2009	Water quality Determination of selected alkylphenols Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation
ISO 16720:2005	Soil quality Pretreatment of samples by freeze-drying for subsequent analysis
EN ISO 18857-2:2011	Water quality - Determination of selected alkylphenols - Part 2: Gas chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2:2009)
EN ISO 16720:2007	Soil quality - Pretreatment of samples by freeze-drying for subsequent analysis (ISO 16720:2005)
ISO 5725-2:1994	Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
ISO 8466-1:1990	Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration function
EN ISO 22892:2011	Soil quality - Guidelines for the identification of target compounds by gas chromatography and mass spectrometry (ISO 22892:2006)