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EN 12916:2016

Superseded

Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

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superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Petroleum products - Determination of aromatic hydrocarbon types in middle distillates - High performance liquid chromatography method with refractive index detection

Superseded date

05-25-2019

Published date

02-17-2016

European foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Reagents and materials
6 Apparatus
7 Sampling
8 Apparatus preparation
9 Calibration
10 Procedure
11 Calculation
12 Expression of results
13 Precision
14 Test report
Annex A (informative) - Column selection and use
Bibliography

This European Standard specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels that may contain fatty acid methyl esters (FAME) up to 30 % (V/V) and petroleum distillates in the boiling range from 150 °C to 400 °C. The polycyclic aromatic hydrocarbons content is calculated from the sum of di-aromatic and tri+-aromatic hydrocarbons and the total content of aromatic compounds is calculated from the sum of the individual aromatic hydrocarbon types.Compounds containing sulfur, nitrogen and oxygen can interfere in the determination; mono-alkenes do not interfere, but conjugated di-alkenes and poly-alkenes, if present, may do so.The precision statement of the test method has been established for diesel fuels with and without FAME blending components, with a mono-aromatic content in the range from 6 % (m/m) to 30 % (m/m), a di-aromatic content from 1 % (m/m) to 10 % (m/m), a tri+-aromatic content from 0 % (m/m) to 2 % (m/m), a polycyclic aromatic content from 1 % (m/m) to 12 % (m/m), and a total aromatic content from 7 % (m/m) to 42 % (m/m).NOTE 1For the purpose of this European Standard, the terms "% (m/m)" and "% (V/V)" are used to represent the mass fraction and the volume fraction of a material respectively.NOTE 2By convention, the aromatic hydrocarbon types are defined on the basis of their elution characteristics from the specified liquid chromatography column relative to model aromatic compounds. Their quantification is performed using an external calibration with a single aromatic compound for each of them, which may or may not be representative of the aromatics present in the sample. Alternative techniques and test methods may classify and quantify individual aromatic hydrocarbon types differently.WARNING - The use of this Standard can involve hazardous materials, operations and equipment. This Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this standard to take appropriate measures to ensure the safety and health of personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this purpose.

Committee
CEN/TC 19
DevelopmentNote
Supersedes PREN 12916. (02/2016)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded
SupersededBy
Supersedes

17/30359196 DC : DRAFT SEP 2017 BS EN 16709 AMD 1 - AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
S.R. CEN/TR 16389:2017 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL AND BLENDS WITH FAME - BACKGROUND TO THE PARAMETERS REQUIRED AND THEIR RESPECTIVE LIMITS AND DETERMINATION
PD CEN/TR 16389:2017 Automotive fuels. Paraffinic diesel fuel and blends with FAME. Background to the parameters required and their respective limits and determination
13/30279896 DC : 0 BS ISO 8178-5 - RECIPROCATING INTERNAL COMBUSTION ENGINES - EXHAUST EMISSION MEASUREMENT - PART 5: TEST FUELS
11/30249539 DC : 0 BS EN 590 - AUTOMOTIVE FUELS - DIESEL - REQUIREMENTS AND TEST METHODS
DIN EN 15940:2016-09 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
S.R. CEN/TS 15940:2012 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
EN 16709:2015/AC:2016 AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
BS ISO 8178-5:2008 Reciprocating internal combustion engines. Exhaust emission measurement Test fuels
EN 15940:2016 Automotive fuels - Paraffinic diesel fuel from synthesis or hydrotreatment - Requirements and test methods
BS EN 16734 : 2016 AUTOMOTIVE FUELS - AUTOMOTIVE B10 DIESEL FUEL - REQUIREMENTS AND TEST METHODS
I.S. EN 16709:2015 AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
BS EN 16709 : 2015 AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
EN 16734:2016 Automotive fuels - Automotive B10 diesel fuel - Requirements and test methods
S.R. CWA 15940:2009 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
14/30298209 DC : 0 BS EN 16734 - AUTOMOTIVE FUELS - AUTOMOTIVE B10 DIESEL FUEL - REQUIREMENTS AND TEST METHODS
PREN 590 : DRAFT 2011 AUTOMOTIVE FUELS - DIESEL - REQUIREMENTS AND TEST METHODS
UNE-EN 16734:2017 Automotive fuels - Automotive B10 diesel fuel - Requirements and test methods
DIN EN 16709 E : 2015 AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
BS EN 590 : 2013 AUTOMOTIVE FUELS - DIESEL - REQUIREMENTS AND TEST METHODS
ISO 8178-5:2015 Reciprocating internal combustion engines Exhaust emission measurement Part 5: Test fuels
I.S. EN 16734:2016 AUTOMOTIVE FUELS - AUTOMOTIVE B10 DIESEL FUEL - REQUIREMENTS AND TEST METHODS
DIN EN 15940 E : 2016 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
14/30310326 DC : 0 BS EN 15940 - AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
DIN EN 590:2017-10 Automotive fuels - Diesel - Requirements and test methods (includes Amendment :2017)
EN 590:2013 Automotive fuels - Diesel - Requirements and test methods
UNE-EN 16709:2016 Automotive fuels - High FAME diesel fuel (B20 and B30) - Requirements and test methods
UNI CEN/TS 15940 : 2012 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS
I.S. EN 590:2013+A1:2017&LC:2017 AUTOMOTIVE FUELS - DIESEL - REQUIREMENTS AND TEST METHODS
DIN EN 16709:2015-12 AUTOMOTIVE FUELS - HIGH FAME DIESEL FUEL (B20 AND B30) - REQUIREMENTS AND TEST METHODS
UNE-EN 15940:2016 Automotive fuels - Paraffinic diesel fuel from synthesis or hydrotreatment - Requirements and test methods
UNE-EN 590:2014 Automotive fuels - Diesel - Requirements and test methods
CEN/TR 16389:2017 Automotive fuels - Paraffinic diesel fuel and blends with FAME - Background to the parameters required and their respective limits and determination
CEN/TS 15940 : 2012 AUTOMOTIVE FUELS - PARAFFINIC DIESEL FUEL FROM SYNTHESIS OR HYDROTREATMENT - REQUIREMENTS AND TEST METHODS

ISO 3171:1988 Petroleum liquids — Automatic pipeline sampling
ISO 3170:2004 Petroleum liquids — Manual sampling
ISO 1042:1998 Laboratory glassware One-mark volumetric flasks
EN ISO 1042 : 1999 LABORATORY GLASSWARE - ONE-MARK VOLUMETRIC FLASKS
ISO 4259:2006 Petroleum products Determination and application of precision data in relation to methods of test
EN ISO 3170:2004 Petroleum liquids - Manual sampling (ISO 3170:2004)
EN ISO 3171:1999 Petroleum liquids - Automatic pipeline sampling (ISO 3171:1988)
EN ISO 4259:2006 Petroleum products - Determination and application of precision data in relation to methods of test (ISO 4259:2006)

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