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EN 14362-1:2012

Superseded
Superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

View Superseded by
superseded

A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.

Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres
Superseded date

02-01-2017

Published date

02-08-2012

Foreword
1 Scope
2 Normative references
3 General
4 Principle
5 Safety precautions
6 Reagents
7 Apparatus
8 Test specimen sampling and preparation
9 Procedure
10 Evaluation
11 Test report
Annex A (informative) - Chromatographic analyses
Annex B (informative) - Reliability of the method
Annex C (informative) - Assessment guide-interpretation
        of analytical results
Annex D (informative) - Explanatory table of dyestuffs
        used in various textile materials
Annex E (informative) - Procedure for liquid/liquid-extraction
        without diatomaceous earth
Annex F (normative) - Colorants - Methods for determination of
        certain aromatic amines
Bibliography

This European Standard describes a procedure to detect the use of certain azo colorants that may not be used in the manufacture or treatment of certain commodities made of textile fibres and that are accessible to reducing agent with and without extraction.Azo colorants accessible to reducing agent without extraction are those used to dye:cellulosic fibres (e.g. cotton, viscose);protein fibres (e.g. wool, silk);synthetic fibres (e.g. polyamide, acrylic).Azo colorants accessible with extraction are those used to dye man-made fibres with disperse dyes. The following man-made fibres can be dyed with disperse dyes: polyester, polyamide, acetate, triacetate, acrylic and chlorofibre.For certain commodities made of cellulose and/or protein fibres blended with man-made fibres it is necessary to extract the dye first.The method is relevant for all coloured textiles, e.g. dyed, printed and coated textiles.

Committee
CEN/TC 248
DevelopmentNote
Supersedes PREN 14362-1 & EN 14362-2. (02/2012)
DocumentType
Standard
PublisherName
Comite Europeen de Normalisation
Status
Superseded
SupersededBy
Supersedes

BS EN ISO 16373-3:2014 Textiles. Dyestuffs Method for determination of certain carcinogenic dyestuffs (method using triethylamine/methanol)
PD CEN/TR 16741:2015 Textiles and textile products. Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery
BS EN ISO 17234-1:2015 Leather. Chemical tests for the determination of certain azo colorants in dyed leathers Determination of certain aromatic amines derived from azo colorants
UNE-EN 71-7:2015 Safety of toys - Part 7: Finger paints - Requirements and test methods
BS EN ISO 13688:2013 Protective clothing. General requirements
UNE-EN ISO 14362-3:2017 Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene (ISO 14362-3:2017)
UNE-EN ISO 16373-1:2016 Textiles - Dyestuffs - Part 1: General principles of testing coloured textiles for dyestuff identification (ISO 16373-1:2015)
UNI CEN ISO/TR 16178 : 2014 FOOTWEAR - CRITICAL SUBSTANCES POTENTIALLY PRESENT IN FOOTWEAR AND FOOTWEAR COMPONENTS
CEN/TR 16417:2016 FOOTWEAR - FOOTWEAR INDUSTRY GUIDELINE FOR SUBSTANCES OF VERY HIGH CONCERN (ANNEX 14 OF REACH)
DIN EN ISO 16373-3 E : 2014 TEXTILES - DYESTUFFS - PART 3: METHOD FOR DETERMINATION OF CERTAIN CARCINOGENIC DYESTUFFS (METHOD USING TRIETHYLAMINE/METHANOL) (ISO 16373-3:2014)
BS EN ISO 16373-1:2015 Textiles. Dyestuffs General principles of testing coloured textiles for dyestuff identification
12/30276376 DC : 0 BS ISO 24362-3 - TEXTILES - METHODS FOR DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS - PART 3: DETECTION OF THE USE OF CERTAIN AZO COLORANTS, WHICH MAY RELEASE 4-AMINOAZOBENZENE
I.S. EN ISO 16373-1:2015 TEXTILES - DYESTUFFS - PART 1: GENERAL PRINCIPLES OF TESTING COLOURED TEXTILES FOR DYESTUFF IDENTIFICATION (ISO 16373-1:2015)
S.R. CEN/TR 16417:2016 FOOTWEAR - FOOTWEAR INDUSTRY GUIDELINE FOR SUBSTANCES OF VERY HIGH CONCERN (ANNEX 14 OF REACH)
DIN EN 14328 E : 2005 PROTECTIVE CLOTHING - GLOVES AND ARMGUARDS PROTECTING AGAINST CUTS BY POWERED KNIVES - REQUIREMENTS AND TEST METHODS
BS EN 14328:2005 Protective clothing. Gloves and armguards protecting against cuts by powered knives. Requirements and test methods
DIN EN ISO 16373-3:2014-10 TEXTILES - DYESTUFFS - PART 3: METHOD FOR DETERMINATION OF CERTAIN CARCINOGENIC DYESTUFFS (METHOD USING TRIETHYLAMINE/METHANOL) (ISO 16373-3:2014)
DIN EN ISO 17234-1:2015-07 LEATHER - CHEMICAL TESTS FOR THE DETERMINATION OF CERTAIN AZO COLORANTS IN DYED LEATHERS - PART 1: DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS (ISO 17234-1:2015)
PD CEN ISO/TR 16178:2012 Footwear. Critical substances potentially present in footwear and footwear components
UNE-EN ISO 16373-3:2015 Textiles - Dyestuffs - Part 3: Method for determination of certain carcinogenic dyestuffs (method using triethylamine/methanol) (ISO 16373-3:2014)
UNI EN 14362-3 : 2012 TEXTILES - METHODS FOR DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS - PART 3: DETECTION OF THE USE OF CERTAIN AZO COLORANTS, WHICH MAY RELEASE 4-AMINOAZOBENZENE
S.R. CEN ISO/TR 16178:2012 FOOTWEAR - CRITICAL SUBSTANCES POTENTIALLY PRESENT IN FOOTWEAR AND FOOTWEAR COMPONENTS (ISO/TR 16178:2012)
I.S. CEN TR 13387:2004 CHILD USE AND CARE ARTICLES - SAFETY GUIDELINES
ISO 16373-3:2014 Textiles Dyestuffs Part 3: Method for determination of certain carcinogenic dyestuffs (method using triethylamine/methanol)
EN ISO 17234-1:2015 Leather - Chemical tests for the determination of certain azo colorants in dyed leathers - Part 1: Determination of certain aromatic amines derived from azo colorants (ISO 17234-1:2015)
EN ISO 16373-3:2014 Textiles - Dyestuffs - Part 3: Method for determination of certain carcinogenic dyestuffs (method using triethylamine/methanol) (ISO 16373-3:2014)
UNE-EN 14362-3:2012 Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene
DIN EN ISO 16373-1 E : 2016 TEXTILES - DYESTUFFS - PART 1: GENERAL PRINCIPLES OF TESTING COLOURED TEXTILES FOR DYESTUFF IDENTIFICATION (ISO 16373-1:2015)
UNI EN ISO 13688 : 2013 PROTECTIVE CLOTHING - GENERAL REQUIREMENTS
DIN EN ISO 16373-1:2016-05 TEXTILES - DYESTUFFS - PART 1: GENERAL PRINCIPLES OF TESTING COLOURED TEXTILES FOR DYESTUFF IDENTIFICATION (ISO 16373-1:2015)
BS EN 14362-3:2012 Textiles. Methods for determination of certain aromatic amines derived from azo colorants Detection of the use of certain azo colorants, which may release 4-aminoazobenzene
BS ISO 24362-1:2014 Textiles. Methods for determination of certain aromatic amines derived from azo colorants Detection of the use of certain azo colorants accessible with and without extracting the fibres
PD CEN/TR 16417:2016 Footwear. Footwear industry guideline for substances of very high concern (Annex XIV of REACH)
DIN EN ISO 13688:2013-12 Protective clothing - General requirements (ISO 13688:2013)
PD CEN/TR 13387:2004 Child use and care articles. Safety guidelines
I.S. EN ISO 16373-3:2014 TEXTILES - DYESTUFFS - PART 3: METHOD FOR DETERMINATION OF CERTAIN CARCINOGENIC DYESTUFFS (METHOD USING TRIETHYLAMINE/METHANOL) (ISO 16373-3:2014)
I.S. EN 14362-3:2012 TEXTILES - METHODS FOR DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS - PART 3: DETECTION OF THE USE OF CERTAIN AZO COLORANTS, WHICH MAY RELEASE 4-AMINOAZOBENZENE
BS EN 71-7 : 2014 SAFETY OF TOYS - PART 7: FINGER PAINTS - REQUIREMENTS AND TEST METHODS
PREN 14041 : DRAFT 2016 RESILIENT, TEXTILE AND LAMINATE FLOOR COVERINGS - ESSENTIAL CHARACTERISTICS
ISO 24362-1:2014 Textiles Methods for determination of certain aromatic amines derived from azo colorants Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres
I.S. EN ISO 17234-1:2015 LEATHER - CHEMICAL TESTS FOR THE DETERMINATION OF CERTAIN AZO COLORANTS IN DYED LEATHERS - PART 1: DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS (ISO 17234-1:2015)
CEN ISO/TR 16178:2012 FOOTWEAR - CRITICAL SUBSTANCES POTENTIALLY PRESENT IN FOOTWEAR AND FOOTWEAR COMPONENTS (ISO/TR 16178:2012)
ISO 16373-1:2015 Textiles Dyestuffs Part 1: General principles of testing coloured textiles for dyestuff identification
ISO/TR 16178:2012 Footwear Critical substances potentially present in footwear and footwear components
ISO 17234-1:2015 Leather Chemical tests for the determination of certain azo colorants in dyed leathers Part 1: Determination of certain aromatic amines derived from azo colorants
EN 14362-3:2012 Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene
EN ISO 16373-1:2015 Textiles - Dyestuffs - Part 1: General principles of testing coloured textiles for dyestuff identification (ISO 16373-1:2015)
EN 14328:2005 Protective clothing - Gloves and armguards protecting against cuts by powered knives - Requirements and test methods
14/30267954 DC : 0 BS EN ISO 16373-1 - TEXTILES - DYESTUFFS - PART 1: GENERAL PRINCIPLES OF TESTING COLOURED TEXTILES FOR DYESTUFF IDENTIFICATION
11/30199139 DC : 0 BS EN ISO 13688 - PROTECTIVE CLOTHING - GENERAL REQUIREMENTS
I.S. EN ISO 13688:2013 PROTECTIVE CLOTHING - GENERAL REQUIREMENTS (ISO 13688:2013)
DIN EN 14362-3:2012-09 TEXTILES - METHODS FOR THE DETERMINATION OF CERTAIN AROMATIC AMINES DERIVED FROM AZO COLORANTS - PART 3: DETECTION OF THE USE OF CERTAIN AZO COLORANTS, WHICH MAY RELEASE 4-AMINOAZOBENZENE
16/30339855 DC : 0 BS EN 14041 - RESILIENT, TEXTILE AND LAMINATE FLOOR COVERINGS - ESSENTIAL CHARACTERISTICS
I.S. EN 71-7:2014 SAFETY OF TOYS - PART 7: FINGER PAINTS - REQUIREMENTS AND TEST METHODS
UNI EN ISO 16373-3 : 2014 TEXTILES - DYESTUFFS - PART 3: METHOD FOR DETERMINATION OF CERTAIN CARCINOGENIC DYESTUFFS (METHOD USING TRIETHYLAMINE/METHANOL)
UNE-EN ISO 17234-1:2015 Leather - Chemical tests for the determination of certain azo colorants in dyed leathers - Part 1: Determination of certain aromatic amines derived from azo colorants (ISO 17234-1:2015)
S.R. CEN/TR 16741:2015 TEXTILES AND TEXTILE PRODUCTS - GUIDANCE ON HEALTH AND ENVIRONMENTAL ISSUES RELATED TO CHEMICAL CONTENT OF TEXTILE PRODUCTS INTENDED FOR CLOTHING, INTERIOR TEXTILES AND UPHOLSTERY
EN 71-7:2014+A2:2018 Safety of toys - Part 7: Finger paints - Requirements and test methods
ISO 13688:2013 Protective clothing — General requirements
CEN/TR 13387 : 2004 CHILD USE AND CARE ARTICLES - SAFETY GUIDELINES
CEN/TR 16741:2015 Textiles and textile products - Guidance on health and environmental issues related to chemical content of textile products intended for clothing, interior textiles and upholstery
EN ISO 13688:2013 Protective clothing - General requirements (ISO 13688:2013)
DIN EN 14328:2005-07 PROTECTIVE CLOTHING - GLOVES AND ARMGUARDS PROTECTING AGAINST CUTS BY POWERED KNIVES - REQUIREMENTS AND TEST METHODS

ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
EN 14362-3:2012 Textiles - Methods for determination of certain aromatic amines derived from azo colorants - Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene

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