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I.S. ENV 14138:2002

Current
Current

The latest, up-to-date edition.

LEAD AND LEAD ALLOYS - ANALYSIS BY FLAME ATOMIC ABSORPTION SPECTROMETRY (FAAS) OR INDUCTIVELY COUPLED PLASMA EMISSION SPECTROMETRY (ICP-ES), AFTER SEPARATION BY CO-PRECIPITATION
Available format(s)

Hardcopy , PDF

Language(s)

English

Published date

01-01-2002

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For Harmonized Standards, check the EU site to confirm that the Standard is cited in the Official Journal.

Only cited Standards give presumption of conformance to New Approach Directives/Regulations.

Foreword
1 Scope
2 Normative references
3 Principle
   3.1 Preparation of the test solution
   3.2 Instrumental techniques
       3.2.1 Flame atomic absorption spectrometry (FAAS)
       3.2.2 Inductively coupled plasma emission
             spectrometry (ICP-ES)
4 Apparatus
   4.1 General
   4.2 Volumetric glassware
   4.3 Filtration system
   4.4 Instruments
       4.4.1 Flame atomic absorption spectrometer
       4.4.2 Inductively coupled plasma emission
             spectrometer
5 Reagents
   5.1 General
   5.2 Nitric acid (HNO[3])
       5.2.1 Concentrated nitric acid
       5.2.2 Nitric acid 1:1 (V/V)
       5.2.3 Nitric acid 1:2 (V/V)
   5.3 Hydrochloric acid (HCI)
       5.3.1 Concentrated hydrochloric acid
       5.3.2 Hydrochloric acid 1:1 (V/V)
   5.4 Ammonia solution
   5.5 Pure lead
   5.6 Manganese nitrate solution
   5.7 Potassium permanganate solution
   5.8 Standard solutions
       5.8.1 Standard solutions (1 g/l)
       5.8.2 Standard solutions (100 mg/l)
       5.8.3 Standard solutions (10 mg/l)
       5.8.4 Multi-element solutions (either 10 mg/l or
             100 mg/l)
6 Sampling and sample preparation
7 Procedure
   7.1 Preparation of the test solution
       7.1.1 Dissolution
       7.1.2 Co-precipitation with manganese dioxide
       7.1.3 Test solution
   7.2 Preparation of the synthetic test solution
   7.3 Preparation of the blank test solution
   7.4 Preparation of the calibration solutions
8 Determination of elements by FAAS
   8.1 General
   8.2 Calibration and measurement of the test solution
   8.3 Expression of results
       8.3.1 Analyte recovery rate
       8.3.2 Analyte content in the sample
9 Determination of elements by ICP-ES
   9.1 General
   9.2 Calibration and measurement of the test solution
   9.3 Expression of results
       9.3.1 Analyte recovery rate
       9.3.2 Analyte content in the sample
10 Test report
Bibliography

Describes methods using flame atomic absorption spectrometry (FAAS) and inductively coupled plasma emission spectrometry (ICP-ES) for the determination of elements at low content in lead for the certain ranges.

DocumentType
Standard
Pages
16
PublisherName
National Standards Authority of Ireland
Status
Current

Standards Relationship
ENV 14138:2001 Identical

EN 12402 : 1999 LEAD AND LEAD ALLOYS - METHODS OF SAMPLING FOR ANALYSIS
ISO 1042:1998 Laboratory glassware One-mark volumetric flasks
ISO 648:2008 Laboratory glassware — Single-volume pipettes
EN ISO 1042 : 1999 LABORATORY GLASSWARE - ONE-MARK VOLUMETRIC FLASKS
ENV 14029:2001 Lead and lead alloys - Analysis by flame atomic absorption spectrometry (FAAS) or inductively coupled plasma emission spectrometry (ICP-ES), after separation of the lead matrix
ISO 3696:1987 Water for analytical laboratory use — Specification and test methods
EN ISO 3696:1995 Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)
ENV 13800:2000 Lead and lead alloys - Analysis by flame atomic absorption spectrometry (FAAS) or inductively coupled plasma emission spectrometry (ICP-ES), without separation of the lead matrix
ENV 12908:1997 Lead and lead alloys - Analysis by Optical Emission Spectrometry (OES) with spark excitation

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