CEN/TS 16190:2012

Name: CEN/TS 16190:2012
Brand: CEN

Superseded

View Superseded by

Sludge, treated biowaste and soil - Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high resolution mass selective detection (HR GC-MS)

Superseded date

14-02-2022

Published date

22-02-2012

Publisher

Comite Europeen de Normalisation

Foreword
Introduction
1 Scope
2 Normative references
3 Abbreviations
4 Principle
5 Reagents
6 Apparatus and materials
7 Sample storage and sample pretreatment
8 Extraction and clean-up
9 HRGC/HRMS analysis
10 Precision
11 Test report
Annex A (informative) - Toxic equivalent factors
Annex B (informative) - Repeatability and reproducibility
        data
Annex C (informative) - Examples of extraction and
        clean-up methods
Annex D (informative) - Examples of operation of GC/HRMS
        determination
Bibliography

This Technical Specification specifies a method for quantitative determination of 17 2,3,7,8-chlorine substituted dibenzo-p-dioxins and dibenzofurans and dioxin-like polychlorinated biphenyls in sludge, treated biowaste and soil using liquid column chromatographic clean-up methods and GC/HRMS.The analytes to be determined with this Technical Specification are listed in Table 2.(...)The limit of detection depends on the kind of sample, the congener, the equipment used and the quality of chemicals used for extraction and clean-up. Under the conditions specified in this Technical Specification, limits of detection better than 1 ng/kg (expressed as dry matter) can be achieved.This method is "performance based". It is permitted to modify the method if all performance criteria given in this method are met.NOTEIn principle this method can also be applied for sediments, mineral wastes and for vegetation. It is the responsibility of the user of this Technical Specification to validate the application for these matrices.

Committee	CEN/TC 444
DocumentType	Technical Specification
PublisherName	Comite Europeen de Normalisation
Status	Superseded
SupersededBy	NEN-EN 16190:2019 en EN 16190:2018

Standards	Relationship
S.R. CEN/TS 16190:2012	Identical
UNI CEN/TS 16190 : 2012	Identical
DIN SPEC 91267 : 2012	Identical
SIS-CEN/TS 16190:2013	Identical
XP CEN/TS 16190 : 2012 XP	Identical
DIN CEN/TS 16190;DIN SPEC 91267:2012-05	Identical

EN 1948-2:2006	Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 2: Extraction and clean-up of PCDDs/PCDFs
PREN 16179 : DRAFT 2010	SLUDGE, TREATED BIOWASTE AND SOIL - GUIDANCE FOR SAMPLE PRETREATMENT
EN 1948-1:2006	Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 1: Sampling of PCDDs/PCDFs
EN 1948-3:2006	Stationary source emissions - Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs - Part 3: Identification and quantification of PCDDs/PCDFs
ISO 18073:2004	Water quality — Determination of tetra- to octa-chlorinated dioxins and furans — Method using isotope dilution HRGC/HRMS
ISO 5725-2:1994	Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method