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  • ASTM D 7423 : 2017

    Superseded A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
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    Standard Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography and Flame Ionization Detection

    Available format(s):  Hardcopy, PDF

    Superseded date:  20-03-2023

    Language(s):  English

    Published date:  10-07-2017

    Publisher:  American Society for Testing and Materials

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    Abstract - (Show below) - (Hide below)

    This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection.

    Scope - (Show below) - (Hide below)

    1.1This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection. This test method is applicable when the hydrocarbon matrices have a final boiling point not greater than 200 °C. Oxygenate compounds include, but are not limited to, those listed in Table 1. The linear working range for oxygenates is 0.50 mg/kg to 100 mg/kg.

    TABLE 1 Oxygenates and Typical Retention Times

    Components

    Retention Time (min)

    Dimethyl ether

    6.18

    Diethyl ether

    8.44

    Acetaldehyde

    8.89

    Ethyl tert-butyl ether

    10.66

    Methyl tert-butyl ether (MTBE)

    10.92

    Diisopropyl ether

    11.22

    Propionaldehyde (Propanal)

    12.00

    Tertiary amyl methyl ether (TAME)

    13.19

    Propyl ether

    14.00

    Isobutylaldehyde

    14.10

    Butylaldehyde

    14.50

    Methanol

    14.91

    Acetone

    15.39

    Isovaleraldehyde

    16.00

    Valeraldehyde

    16.10

    2-Butanone (MEK)

    17.14

    Ethanol

    17.51

    N-propyl alcohol and isopropanol

    19.20 (co-elution)

    Allyl Alcohol

    20.00

    Isobutanol, Tert-butyl alcohol, Sec-Butanol

    20.24 (co-elution)

    N-butanol

    20.84

    1.2This test method is intended to determine the mass concentration of each oxygenate in the hydrocarbon matrix. Oxygenate compound identification is determined by reference standards and column elution retention order.

    1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

    1.5This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    General Product Information - (Show below) - (Hide below)

    Committee D 02
    Document Type Test Method
    Publisher American Society for Testing and Materials
    Status Superseded
    Superseded By
    Supersedes

    Standards Referencing This Book - (Show below) - (Hide below)

    ASTM D 4175 : 2020 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2014 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2009 : REV A : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6300 : 2020 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2008 : REV B : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6849 : 2022 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 6300 : 2013 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2005 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2010 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6300 : 2014 : REV A : EDT 1 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 1265 : 1997 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
    ASTM D 4175 : 2005 : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2013 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM E 177 : 1990 : REV A : R1996 Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
    ASTM D 4175 : 2015 : REV C Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2017 : REV A Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2020 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2017 : REV A : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2017 : REV B Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6300 : 2017 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 6299 : 2009 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 1835 : 1997 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 6849 : 2002 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 6300 : 2017 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2008 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2020 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2013 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2017 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2021 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2009 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6849 : 2002 : R2012 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 6299 : 2010 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2022 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2022 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6300 : 2016 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2009 : REV A : EDT 4 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2009 : REV A : EDT 3 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6849 : 2002 : R2007 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 6300 : 2004 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2018 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1835 : 2018 : REV A Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 1835 : 2012 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 6300 : 2019 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2001 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2020 : REV B : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2001 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2005 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2022 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6300 : 2021 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6300 : 2019 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2002 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6849 : 2013 : R2021 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 6300 : 2020 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2000 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6299 : 2010 : EDT 2 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6299 : 2016 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2015 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2002 : REV A : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2019 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 1835 : 2003 : REV A Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 6300 : 2020 : REV B Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2000 : REV A Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6300 : 2006 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2009 : REV A : EDT 5 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2016 : REV C Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2015 : REV B Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6300 : 2014 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM E 355 : 1996 : R2021 : EDT 1 Standard Practice for Gas Chromatography Terms and Relationships
    ASTM D 1835 : 2003 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 6300 : 2015 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2015 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6300 : 1999 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 1835 : 2013 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 4175 : 2009 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 1835 : 2020 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 4175 : 2016 : REV B Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6299 : 2020 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2002 : REV A : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2008 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2008 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 1835 : 2018 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 4175 : 2002 : REV A Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6849 : 2013 Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods
    ASTM D 4175 : 2000 : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 4175 : 2016 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1265 : 2004 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
    ASTM D 6300 : 2013 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 6299 : 2002 : EDT 1 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2019 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1835 : 2022 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 4175 : 2022 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1835 : 2016 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 6300 : 2008 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 6300 : 2003 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 1265 : 2011 : R2017 : EDT 1 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
    ASTM D 6300 : 2007 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 6299 : 2022 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2017 : REV A Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1835 : 2011 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 1265 : 2005 Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
    ASTM D 6300 : 2002 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2009 : REV A : EDT 2 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 1265 : 2004 : REV A Standard Practice for Sampling Liquefied Petroleum (LP) Gases (Manual Method)
    ASTM D 1265 : 2011 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
    ASTM D 4175 : 2018 : EDT 1 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 4175 : 2016 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6300 : 2016 : REV A Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM E 355 : 1996 : R2014 Standard Practice for Gas Chromatography Terms and Relationships
    ASTM D 6299 : 2007 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6299 : 2007 : EDT 1 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 6299 : 2020 : REV A Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2017 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 1265 : 2022 Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method
    ASTM D 6299 : 2017 Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
    ASTM D 4175 : 2019 Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
    ASTM D 6300 : 2014 Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products and Lubricants
    ASTM D 4175 : 2015 : REV B : EDT 1 Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 1835 : 2005 Standard Specification for Liquefied Petroleum (LP) Gases
    ASTM D 4175 : 2008 : REV B Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants
    ASTM D 6299 : 2002 Standard Practice for Applying Statistical Quality Assurance Techniques to Evaluate Analytical Measurement System Performance
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